Schiff碱N-(4-羟基苯基亚甲基)-对甲氧基苯胺的室温固相合成及表征.pdfVIP

理ff!，蓝蓝-fl!霎金回 PTCA(PART B: CHEM. ANAL.) Schiff 碱 N-(4-瓷基苯基亚甲基)­ 对甲氧基苯肢的室温固相合成及表征 李人宇1 ， 2 ，李咏梅1.3 ，杨绪杰1 ，陆路德1 ，汪信1 (1.南京理工大学材料化学实验室，南京 210094; 2. 连云港师范高等专科学校，连云港 222006; 3. 淮海工学院化工系，连云港 222005) 摘要:对甲氧基苯接与对美圣基苯甲睦通过室温罔相反应一步合成 N-(4-在基苯基亚甲基)-对 甲氧基苯滕(C H N0 ) ，反应在 15 min 内完成，产率 93% ，分别用元素分析、红外光谱、X 射线粉 14 13 2 末衍射谱和核磁共振氢谱对产物进行了表征。 关键词:固相合成; N-(4-是基苯基亚甲基)对甲氧基苯滕;表征 中固分类号: 0625.632 文献标识码:A 文章编号: 1001-4020(2007)04-0293-03 Solid Phase Synthesis of N-(4-Hydroxyphenylmethylene)-p-Methoxyaniline at Room Temperature and Its Characterization 1 1 1 1 LI Ren-yu ,2 , LI Yong-mei 1.3 , YANG X u-jie , LU Lu-de , WANG Xin (1. Material ChemìstηLaboratory ， Nanjing Unì7.肝sity 0/ Scìence and Engineering , Nanjìng 210094 , China; 2. Lianyungang Teachers College , Lìanyungang 222006 , Chìna; 3. Deparτment 0/ Chemical Engineering , Huaihai Institute 0/ Engineering , Lianyungang 222005 , China) Abstract: N-( 4-hydroxyphenylmethylene)-p--methoxy aniline was synthesized in on巳 step by the reaction between p-methoxyaniline and p-hydroxybenzaldehyde at solid state and under room temperature (30 C). The reaction was finished within 15 min , giving a yield of 93%. The product was characterized by elementary analysis , infrared spectrometry , X-ray diffraction spectrographic method (powder method) and 1H NMR. Keywords: Solid phase synthesis; N-(4-hydroxyphenyl-methylene)-户methoxyaniline; Characterization Schiff 碱含有一RC=N-基团，由醒或酣与伯 磁共振氢谱对产物进行了表征和研究。 胶发生缩合反应生成[I ， 2J 。由于具有杀菌抗病毒∞、 1 试验部分 可逆结合氧气川、非线性光学〔气光致和热致