MgO-C耐火材料的显微组织与加入TiO2和Al的关系,.pdf

Journal of the European Ceramic Society 27 (2007) 73–78 Microstructure evaluation of MgO–C refractories with TiO2- and Al-additions ´ ´ ∗ ´ C.G. Aneziris, J. Hubalkova , R. Barabas Institute of Ceramic, Glass and Construction Materials, Technical University of Freiberg, Germany Received 5 November 2005; received in revised form 13 March 2006; accepted 17 March 2006 Available online 3 May 2006 Abstract The effect of TiO - and Al-additions on the oxidation resistance and the mechanical properties of MgO–C refractories is evaluated in terms of a 2 phase evolution as a function of the coking temperature. The formation of TiCN and TiC crystalline phases in the bonding matrix contributes to superior mechanical, thermal and chemical properties of carbon-bonded refractories. © 2006 Elsevier Ltd. All rights reserved. Keywords: Refractories; MgO; Mechanical properties; Oxidation resistance 1. Introduction Hardenable artificial resins, especially phenolic resins, are an environment-friendly alternative to benzo[a]pyrene rich coal- Magnesia–carbon bricks are established high duty refractory tar pitch and are the most frequently used organic binder in the products with unique mechanical, thermal and chemical proper- production of magnesia–carbon bricks. They can be mixed with ties for applications in converters, electric arc furnaces a