Ni催化剂在N2ON2NH3中退火对碳纳米管表面结构及场发射特性的影响.pdfVIP

新型炭材料 Vo l. 23 No.4 第 23 卷第4 期 NEW CARBON MATERIALS Dec. 2008 2008 年 12 月 Article ID: Iω7-8827(2 8 )04..()302 -O7 ω Effects of annealing Ni catalyst in nitrogen-containing gases on the surface morphology and field幽emission properties of thermal chemical vapor deposited carbon nanotubes Shih嗣Fong Lee. Yung-Ping Chang , Li嗣Ying Lee (Department 0/ Electrical Engíneeríntr. Dayeh IJnÍ!思rsity. Chan{{hlω• China) Abstract: Ní catalyst was annealed ìn N~O/N~/NH， in order to study the effects of the annealing on the surface mor- phology and field嗣emission charactcristics of syn由csízed carbon nanotubes (CNTs).ηlC morphology and composition of the CNTs show that the grain sìze and composition of the Ni catalyst can be modified by N,O. N , and NH可 pre町eat­ 2 ments. Scanning electron microscopy images of evaporated Ni after N 0 pretreatment show that the Ni particles are more 2 uniformly distributed , and their sízes are relatively small. lt is found that the CNT自 grown on Ni pretreated wíth N,O have the highest surface density and the highest emission cu盯ent. Thìs improvement is accomplished through the more uniformly distributed and smaller Ni particles obtained by N,O pretreatment. Thc growth of amorphous car