基于银镜反应的硅银复合负极材料的制备及其表征.pdfVIP

第口期 无机化学学报 Vo l.23 No .l2 CHINESE JOURNAL OF INORGANIC CHEMISTRY Dec. , 2∞7 2∞7 年 12 月 基于银镜反应的硅/银复合负极材料的制备及其表征 杨学林*.1 温兆银2 张露露1 游敏1 林祖罐2 c 三峡大学机械与材料学院，宜昌 443002) f 中国科学院上海硅酸盐研究所，上海 200050) 摘要:基于银镜反服，在动态下用稀氨水将银氨配离子还原为纳米银颗粒，并沉积在硅颗粒袋阁。与常用含银复合材料之银直在 直接还版法和硝酸戴高温分解法相比，配佼还原法具有制备工艺简单快速、银颗粒分散度离和银盐转化率高等特点。得到的硅/ 银复合材料中粒径小子 20 nm 的银颗粒均匀分布在敲颗粒袭阁，无其他杂质梢。与纯磁粉负极相比，磁/银复合材料(含银 l 队Nt9毛)能有效抑制礁负板在循环初始阶段的容量快速表减，30 次循环可逆容赣太子 500 mAh g-I 0 交流阻扰测试~示，纳米银 颗粒的存在能显著提高电子电导，进而改善磁负极的循环稳定性。 关键词:硅/银复合材料:负极;健离子也池 中图分类号: 0613.72; 0614.122; TM912.9 文献标识码:A 文章编号: 1∞1 -4861(2∞17) 12-2054-05 Preparation and Characterization of Silicon!Silver Anode Materials YANGXue孔in代， WEN Zhao-Yin2 ZHANG Lu-Lu YOU Min LIN Zu-Xian矿 CGolle萨 ofMechanical mul M.耐rial Engineering, Three Gorges Univw时.， Yichang, Hubei 443ω2) fSha咽hai lnstitute of Geramics, Chinese Academy of Scienc帆蜘啪ai 200050) Abstract: Silicon/Sílver composite with nano-sized silver particles was synthesized based on principle of a disturbed silver-mirror reaction. Comparing with the direct method , highly dispersed nano帽sílver particles are easier to be obtained by the present method with simple preparation technology and high productivity of silver. Silver particles with particle size le喃自 than 20 nm were uníformly di日persed on the surface of silicon particles , no any other phase except silicon and silver could be observed in the composíte. The composite wi出 1仇竹% of silver could deliver a reversible capacíty more than 500 mAh g- after 30 cycles. AC impedance spectra indicate that existence of nano-silver is favorable to electrical conductivity; therefore , cycleability o