室温仿生合成羟基锡酸锌微球及其表征.pdfVIP

无机盐工业 第 46 卷第 4 期 10 INORGANIC CHEMICALS INDUSTRY 2014 年 04 月 E噩噩噩 室温仿生合成起基锡酸铸微球及其表征* 徐建中，李光明，焦运红，王春征，邵奕嘉 (河北大学化学与环境科学学院，河北保定 071002) 摘 要:主要以七水硫酸伴和三水锡酸纳为原料，以氨水为软模板，用β-环糊精作为有机调控基质，在室温条件 下成功制备了经基锡酸钵微球。对β-环糊精的用量、反应物物质的量比、反应物浓度等条件对产物形貌的影响进行 了探讨。确定程基锡酸钵最佳合成条件为:严-环糊精的用量为 9 g/L;铸离子和锡酸根离子的物质的量比为 2:3; 反应 物浓度为 0.3 molJL。采用 XRD、 SEM 及 TG-DTA 对样品进行了表征和分析，并对资基锡酸铐微球的形成机理做了初 步探讨。 关键词:短基锡酸铮;微球;β-环糊精 中图分类号:TQ132.4 1 文献标识码:A 文章编号:1006-4990(2014)04-0010-04 Biomimetic synthesis and characterization of zinc hydroxystannate microspheres at room temperature Xu Jianzhong ,Li Guangming ,Jiao Yunhong ,Wang Chunzheng ,Shao Yijia (College ofChemistry Environmenta1 Science ,Hebei University ,Baoding 071002 , China) Abstract: Using ZnS04 7H 0 and Na2Sn03 3H 0 as raw materiaIs ,ammonia as 80ft templates ， andβ-cyclodextrin ( CD) con- 2 2 trolling the morphology ,zinc hydroxystannate [ZnSn ( OH ) 6 ] microspheres were prepared at room temperature.The effects of the dosage ofβ-CD ， the amount-of-substance ratio of the reactants ,and the reactant concentration etc.on the product s mor- phology were discussed.The optimum reaction conditions were as follows: the dosage ofβ-CD was 9 g/L, the amount-of-sub- stance ratio 2 of the reactants was n (Zn +) :n(Sn032-) =2:3 ,and the reactant concentration was 0.3 mollL.The products prepared were characterized and anaIyzed by X-ray diffraction(XRD) ,scanning electron microscope(SEM) ,and thermaI anaIysis(TG- DTA). Moreover ,the reaction mechanis