小口径聚氨酯多孔管的制备与表征.pdfVIP

第42 卷第5 期 塑料工业 . 112 . CHINA PLASTICS INDUSTRY 2014 年5 月 小口径聚氨醋多孔管的制备与表征* 高云龙，李洁华*\谭鸿 (高分子材料工程国家重点实验室四川大学高分子科学与工程学院，四川成都 610065) 摘要:首先合成聚酷型聚氨醋和聚硅氧烧改性聚氨酣并设计制作小口径聚氨醋多孔管的模具，调节聚氨醋溶液浓 度，以及聚酷型聚氨醋和聚硅氧烧改性聚氨醋的比例，采用冷冻干燥的方法制备出了一系列不同孔径和结构的小口径 聚氨醋多孔管和多孔膜。通过扫描电镜表征不同浓度含量多孔管的孔径大小、数量及分布。通过 x- 光电子能谱和接 触角表征了聚氨醋多孔膜的表面元素分布和亲疏水性能。结果表明， 8% 的聚酷型聚氨醋，及其与 20% 和 30% 聚硅氧 烧改性聚氨醋共福形成的小口径多孔管孔径和孔的分布上较均匀，为小口径聚氨醋人工血管的制作奠定了实验和理论 基础。 关键词:多孔;微管;聚氨醋;聚硅氧皖 DOI: 10. 3969/j. issn. 1005 - 5770.2014.05.027 中图分类号: TQ316.6 文献标识码:A 文章编号: 1005 -5770 (2014) 05 -0112 -05 Preparation and Characterization of Small Diameter Polyurethanes Porous Tubes GAO Yun-long , LI Jie-hua , TAN Hong (The State Key Laboratory of Polymer Materials Engineering , College of Polymer Science Engineeri吨， Sichuan University , Chengdu 610065 , China) Abstract: Polyether polyurethane and polysiloxane polyurethane were synthesized and the experimental glass mold for small-diameter polyurethanes porous tubule was designed and prepared. Polyurethane solution , the ratio of polyether polyurethane and polysiloxane polyurethane were adjusted , and then a series of small diameter polyurethane porous tubes and porous membranes with different pore sizes and structures were prepared by freeze drying method. The pore size , number and distribution of the porous tubes with different concentrations were studied by scanning electron microscope (SEM). The surface hydrophilic and hydrophobic properties and element distribution of polyurethane porous