对甲苯磺酸(PTSA)对DAST晶体生长、表征的影响.pdfVIP

人工晶体学报 第45 卷第2 期 Vo1. 45 No.2 2016 年2 月 JOURNAL OF SYNTHETIC CRYSTALS February ,2016 Effect of Toluene-sulfonic Acid (PTSA) on the Growth and Characterization of DAST Single Crystals 1 l HAO Lun l.2, TENG Bingl ,2 , CAO Li -feng ,2 , ZHONG De-gω， 1 ， 2 ， SUN Qingl ,2 , YOU Fei , 2 , CHANG Qingl ,2 ( 1. College of Physìcs , Qingdao Unìversity , Qìngd剧， 26创71 ， Chìna; 2. Key Laboratory of Photonìcs Materials and Technol鸣y ìn Unìve四ities of Shando吨， Qingdao 266071 , China) (Received 1 Ocωber 2015 , accepted 21 December 2015) Abstract:4-N , N-dimethylamino-4 :N 二methyl stilbazolium tosylate (DAST) crystals were grown from methanol solutions added with toluene-sulfonic acid (凹SA) .四e metastable zone widths (MZW) of DAST solutions with and without PTSA were measured. lt was found that PTSA could enhance the MZW significantly. The crystal structure and functional groups of the grown DAST were investigated by powder XRD and Fourier transform infrared (ITIR) , respectively. The results indicated that PTSA did not change the crystal structure , The stability of solution with PfSA was helpful to the growth of large size DAST crystal. Key wor由:crγstal growth; PTSA; DAST; metastable zone width CLC number: 078 Document code: A Article ID: 1αlO-985X( 2016 )02-O540{泊 对甲苯磺酸(凹SA) 对 D