对甲苯磺酸掺杂聚吡咯的合成、表征及其对金属镁的防腐蚀性能研究.pdfVIP

吮且66.2008 100S筝属结 化学学报 第5 .111!.571 -575 ACTA CHlMlCA SIl吨lCA No. 5. 571-575 · 研究论文 · 对甲苯磺酸掺杂聚毗暗的合成、表征及其对金属镶的防腐蚀性能研究 黄可龙* 黄健涵 李倩倩 刘素琴 关鲁雄 {中南大学化学化工学院 *沙 41∞83) 要 以对甲苯磺酸为掺杂剂，三氯化铁为氟化剂.化学氧化毗咯制备了对甲苯曲曲1l2~骨杂聚毗咯.考察了掺杂~J与氟 化剂的朋量对掺杂聚毗咯电导率的影响.得到了高咆导率聚毗咯的优化条件.用 UV. IR 和SEM 对其结构和形貌送行 了:a征.结巢褒明.n(对甲苯磺酸) : n(毗咯) : n(三氯化铁)=0.75 : 1 : 0.5 时.合成的聚毗同岛的形貌规则.电导率达42.7 S吨m-. 以聚毗咯为功能成分，环氯树nlî为成膜物质.得到一种功能膜.能涂于金属锁表面.采用极化曲线和开各电位 考察了含有聚毗咯的膜层对金属镑的防腐蚀性能. 结果表明.含有聚毗咯的腆层对金属锐有很好的防腐蚀性能，腐蚀 电流为 0.0981 A，腐蚀电位为-0.88V. 在腺!三与金属镇之间形成了一层钝化麟. 关键词对甲苯磺酸; 聚毗咯;掺杂;电导率;防腐蚀 Synthesis and Characterization of Polypyrrole Doped by p-Tolyl Sulfonic Acid and Its Ant icorrosion Property for Magnesium 口， Qian-Qian HU ANG , Jian-Han LIU, Su-Qin GUAN, Lu-Xiong HUANG, Ke- Long* (College 01 Chemislry and Chemlcal Eng饥eering. Central Soulh Univtrslry. Changsha 4100(3) Abstract Polypyrrole doped by p -tolyl sulfonic acid was chemica11y synthesized 台。m pyπole using p- tolyl sulfonic acid as a doping agent and ferric ch10ride as an oxidant. The effect of dosage of the doping agent and the oxidant on 由e ∞，nductivity of doped polyp严role was investigated, and 由eop山nized ∞ndi­ tions were obtained. 币le molecular structure of 也e polyp归role was characteriz.ed by UV and IR spectra, and its morphology was srudied by SEM. 节le results indicated 也at 由e polypyrrole was regul缸， and its conduc- tivity reached 42.7 S.cm- 1, when the ratio of n(p-tolyl sulfonic acid) : n(pyrrole) : n(ferr