小角X射线散射表征AOT水层状溶致液晶的有序性.pdfVIP

物理化学学报(Wuli Huαxue Xuebao) . September Acta Phys. -Chim. Sin叫 2005， 21(9): 1055-1058 1055 Study of Ordering for AOT/Water Lamellar Lyotropic Liquid Crystal: Small-angle X-ray Scattering Experiments* ZHUANG, Wen-Chang CHEN, Xiao YANG, Chun-Jie WANG, Lu-Yan CHAI, Yong-Cun (Key Laboratory of Colloid and Interface Chemist.η， Minist.η ofEducation, Shandong University, Jinan 250100) Abs位act Small嗣angle X-ray scattering (SAXS) is utilized to study 由e ordering of AOT/water lamellar phase. As increasing surfactant concentration, temperaωre or adding cosurfactant in certain range，伽e arrangement of hydrocarbon chains will change from sparseωdense which results in the strucωral transformation of lamellar p,hase from flexible to planar bilayers. 咀1巳 possible mechanism is proposed based on shape factor and molecular interactions. Molecular simulations are also carried out to 阳盹the obtained r咆sults. Keywords: SAXS, Molecular simulation, Lamellar phase Lyotropic liquid crystal 亿.LC)， depending on type of molec- studying org创垃zed molecular assemblies[12-13J. Based on SAXS ular assembling, is capable to reach special structure of aggre幡 results , various phases with different Bragg peaks can be char峭 gation by varying surfactant concen位ation and temperature 口气 acterized and their long翩rang巳 ordering is obtained, so that 也E Among 也em， lamellar phase is widely studied as a good tem翩 interaction between moleculωand 由e stabilization scheme of plate due to its stability and long翩range periodic structure阴. Asa system can be explored[l4-151. In this paper ,