微波辅助合成石墨烯氧化镍复合材料及其表征.pdfVIP

Vo1.30 No .3 无机化学学报 第 30 卷第 3 期 2014 年 3 月 CHINESE JOURNAL OF INORGANIC CHEMISTRY 609-614 微波辅助合成石墨烯/氧化镇复合材料及其表征 黄子东张海燕*陈易明王文广 洪田惺叶翼鹏雷兴领 (广东工业大学材料与能源学院，广州 51∞06) 摘要:本文通过微波辅助的方法，快速而有效地在热膨胀石墨烯(RG)的缺陷上原位合成氧化镰纳米颗粒，形成石墨烯/氧化镰复 合材料(RG/NiO)。利用 x-射线衍射(XRD) ，拉曼光谱 (Raman) ，傅里叶变换红外(FTIR)，扫描电镜(SEM) ，透射电镜口EM) ，热重-差热 σGA-DSC)对所制备样品的结构、形貌和 NiO 在复合材料中的含量进行表征。结果表明，热膨胀石墨烯层数约 7-8 层，层间距约 为 0.35 nm ，缺陷多，在水热和微波处理后抗氧化性明显变差。复合材料中氧化镇颗粒平均粒径为 25 nm，均匀而密集地分散在 石墨烯平面上，同时在复合材料中的含量为 19.8%。 关键词:热膨胀石墨烯;氧化镰;石墨烯/氧化镰复合材料 中图分类号: 0613.71; TB33 文献标识码:A 文章编号: 1 ∞1 -4861(2014)03-悦。9-06 DOI: 10. 11862/C1IC.2014.114 Microwave-Assisted Synthesis and Characterization of Graphene/NiO Composites Material HUANG Zi-Dong ZHANG Hai-Yan* CHEN Yi-Ming WANG Wen-Guang HONG Tian-Xing YE Yi-Peng LEI Xing- Ling (School 01Malerials and energy, G阳~gdo唔 University 01 Technology, Guangzhou 510∞6， China) Abstract: Graphene/nickel oxide composites (RG/N iO) were prepared by microwave-assisted in-situ synthesis of nano-particles NiO on 由e defects of thermal expansion graphene (RG). 四川tructure， morphology and the NiO content of the composites were characterized by X-ray diffraction (XRD) , Raman spectra (Raman) , Fourier transform infrared (凹lR)， scanning electron microscopy (SEM) , transmission electron microscopy 口EM) and thermogravimetry-differential thermal analysis σGA-DSC).咀le results show that the number of high-defects graphene layers is about 7 斗 and the interlay spacing is around 0.35 nm. Mter hydrothermal reaction and microwave irradiation, the oxidation resistance of graphene became p∞r obviously. The nanoparticles NiO with an average diameter of 25