分离镍和铜(国外英语资料).doc

分离镍和铜(国外英语资料) Recovery of metallic copper and nickel sulfate from waste oil catalysts (Luo Guangming) Recovery of metallic copper and nickel sulfate from spent catalyst in hardened oil Guang Ming Luo (Anhui chemical engineering school, Anqing, 246005) This paper deals with the production of solid wastes from chlor alkali industry, namely, the spent catalyst for hardening oil, and the preparation of copper and nickel sulfate by acid dissolution, removal of iron, electrolysis and analytical process. Keywords hardening oil; spent catalyst; removal of iron; electrolytic voltage; Hardened oil waste catalyst is based on vector dimension diatom and the bioavailability of nickel carbonate mixture into the iron industry after using multi word (Fe2+ and Fe3+), and the loss of catalytic activity was scrapped. There are hundreds of tons of waste catalysts for the production of chlor alkali in the hydrogenation process. The content of copper and nickel in the waste catalyst is 5%, and it has the full use of economic value. 1 process 1.1 process recovery of copper and nickel sulfate from spent oil catalysts, as shown in figure 1. Spent catalyst Acid dissolution Filtration Acid washing 10% sulfuric acid 10% sulfuric acid Iron removal Wash diatomite 3% hydrogen peroxide 10% sodium hydroxide Electrolysis Electrolytic copper, industrial nickel electrolyte Analysis Nickel sulfate crystal 10% sodium hydroxide concentrated sulfuric acid Fig. 1 process flow diagram 1.2 acid solution adds 10% sulfuric acid to the waste catalyst to convert copper and nickel into soluble sulfates. Filtration separation of diatomite, two times adding 10% sulfuric acid, after washing and drying, can be recycled diatomite. 1.3 iron sulfate solution contains iron (Fe, 2+ and Fe, 3+), if not removed, will interfere with the preparation of copper and nickel sulfate. A small amount of 3% hydrogen peroxide is added to oxidize Fe and 2+ to form Fe 3+. Slowly add 10% sodium hydroxide, and continuously determined to