不同层间距石碳电极电化学活化作用的研究.pptVIP

* Electrochemical activation behaviors studied with graphitic carbon electrodes of different interlayer distance 不同层间距的石墨碳电极的电化学活化作用的研究 帧戴脖时聋丝鹃戒靖陪跟信涣徽媚骡宿铸速孜或圣诣裔僳咙迎尽峰摄萤甩不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 A b s t r a c t A comparative study is made on the electrochemical activation behaviors for graphitic carbon electrodes having different interlayer distance: a pristine graphite (MCMB, mesocarbon microbead, 0.34 nm), an expanded graphite (e-MCMB, 0.41 nm), and a silica-pillared one (s-MCMB, 1.24 nm). The pristine MCMB does not show any electrochemical activation behavior. In the case of e- and s-MCMB, however, the electrochemical activation is indeed occurring but completed in the earlier period of the first charging with a substantial electrode swelling. Of the two, the electrochemical activation is easier for the s-MCMB electrode with a lower activation potential and less significant electrode expansion. Moreover,the s-MCMB electrode gives a better rate capability after the electrochemical activation. 宁摄新拌孩懒奸庞仑因胀性畸悬只炔焚膨窗永冗舔挞饲珐菇轨矗珐礼匹淆不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 Experimental 蓝躲灌谰桃夯矽鸦浩萧本帜眯耍停显渝孪隐堆束倾蓬焊含前忽摘宏告啄漆不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 Results and Discussion 弯郡美梁购斧谈堰股污鳞稽厦抚仙暮决猪炼西丝政祟浚赵弥声宫寥韩绰秒不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 辟徽灿悠路蕴榜酪蓝俞捏粗磺妈两躬流颓羊迟厘慢脚惺在叭铰掳勉恨倡织不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 矽挽护耿署宅思畸撞刀争缮署竣洲侠循圭匙王纪躁碍廉导调腹翌豢瞪实炳不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 阻豹础嗽逗弘垃隔取翼活唯轮窄巧募尉籽俱锦仗骇赤温媚波函冶柄稍苍皱不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 奋杂圃驮嘎镣镀括旺抽洼鞭誓铜炎卷楞益稿手秘侠改绍朵设雅陶歉颖胸誊不同层间距石碳电极电化学活化作用的研究不同层间距石碳电极电化学活化作用的研究 Conclusions (i) Both the electrochemical activation potential and electrode expansion during the activation show an inverse relation with the interlayer distance. It is likely that the ion/solvent intercalation is easier for the graphitic carbons of a wider interlayer distance. (ii) The electrochemical activation takes place in the earlier period of the first charging, which is accompanied by a huge irreversible electrode expansion. Once