快淬对 RE-Mg-Ni-Mn 系 AB2型贮氢合金结构及电化学性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 26(2016) 3219−3231 Effects of spinning rate on structures and electrochemical hydrogen storage performances of RE−Mg−Ni−Mn-based AB -type alloys 2 1,2 1 3 3 3 2 Yang-huan ZHANG , Wei ZHANG , Xi-ping SONG , Pei-long ZHANG , Yong-guo ZHU , Yan QI 1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China; 2. Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, China; 3. Whole Win (Beijing) Materials Sci. Tech. Co., Ltd., Beijing 100083, China Received 8 December 2015; accepted 18 April 2016 Abstract: La was partially substituted by Ce with the aim of improving the electrochemical hydrogen storage performances of La1 Ce MgNi Mn (x=0, 0.1, 0.2, 0.3, 0.4) alloys, and melt spinning technology was adopted to fabricate the alloys. The –x x 3.5 0.5 identification of XRD and SEM reveals that the experimental alloys consist of a major phase LaMgNi and a secondary phase LaNi . 4 5 The growth of spinning rate results in that the lattice constants and cell volume increase and the grains are markedly refined. The electrochemical measurement shows that the as-cast and spun alloys can ob