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树枝状结构膦配体的设计合成及其在催化中的应用论文
Abstract
havebeen much
dendrimers attentiondue
Organometallic attracting
their chemicaland havethe
to unique properties.Theypotential
physical
the and
tocombine of catalysis.
homogeneousheterogeneous
advantages
dendrimerswith
Inthis of the active
thesis,two
types catalytically
at andatthecoreofthedendrimer
centerslocatedthe were
periphery
and in reactionssuch
catalytic
synthesized.Theirapplications
designed
the betweendendritic
as and
ofolefius
hydrofor|∞yla.tion relationships
havealSO discussed.Some
and been
structure
catalyticproperty
follows:
results as
wereobtained
scientific
1.Threenewkindsofdendritic PPh3
ligands
triphenylphosphrous
thedendrimerhavebeen
locatedatthe of synthesized
periphery by
Rh were and
method.1heir
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