氮化铝纳米线的气–固法制备及光学性能 - Ingenta Connect.PDFVIP

· 1898 · 硅 酸 盐 学 报 2011 年 第39 卷第12 期 硅 酸 盐 学 报 Vol. 39 ，No. 12 2 0 1 1 年 1 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY December ，2011 氮化铝纳米线的气– 固法制备及光学性能 崔静雅，吕惠民，程赛 (西安理工大学应用物理系，西安 710054) 摘 要：以三氯化铝和叠氮化钠为原料，用复分解反应制备单晶氮化铝(AlN)纳米线。样品呈灰白色粉末，反应温度为650 ℃，反应时间为3 h ，并对 该样品进行X 射线衍射、透射电镜和选区电子衍射测试分析。结果表明：样品为六方相氮化铝且为表面光滑的长直形圆柱状，直径为 50 nm 左右， 长度均在10 μm 以上，晶格常数分别为a = 0.268 nm 、c = 0.498 nm 。AlN 样品性能的研究表明：样品禁带宽度约为6.14 eV，并对光致发光谱中各峰的 形成原因进行分析。采用气– 固生长机理和择优取向原理对单晶纳米线的生长进行解释。 关键词：氮化铝纳米线；复分解反应；气– 固机理；光学性能；择优取向 中图分类号：TB34 文献标志码：A 文章编号：0454–5648(2011)12–1898–06 网络出版时间： DOI ： 网络出版地址： Vapor–Solid Method and Optical Properties of Aluminum Nitride Nanowires CUI Jingya，LÜ Huimin ，CHENG Sai (Department of Applied Physics, Xi′an University of Technology, Xi′an 710054, China) Abstract: Single-crystal AlN nanowires were prepared via double decomposition reaction, in which AlCl and NaN were used as raw 3 3 materials. Samples were grayish white powder with reaction temperature of 650 ℃ and reaction time of 3 h. The AlN nanomaterials were tested by X-ray diffraction, transmission electron microscopy, and selected area electron diffraction. It is indicated that the sam- 硅酸盐学报 ples are hexagonal AlN nanowires of long straight cylinders with a smooth surface about 50 nm in diameter and more than 10 μm in length, and its lattice constants are a = 0.268 nm, c = 0.498 nm. Performance test of the as-prepared samples shows that band-gap is 6.14 eV. The formation cause of each peak o