KOH 的活化作用在超电中的应用 组会报告 KOH Activation insupercapacitors.pptVIP

The Research of KOH Activation Reporter : xxx 2KOH →K2O + H2O (1) C + H2O →CO + H2 (2) CO + H2O→ CO2 + H2 (3) CO2 + K2O→K2CO3 (4) T. Otowa, R. Tanibata and M. Itoh, Gas Sep. Purif., 1993, 7, 241. D. Lozano-Castello, J. M. Calo, D. Cazorla-Amoros and A. Linares-Solano, Carbon, 2007, 45, 2529. 6KOH + 2C →2K + 3H2 + 2K2CO3 (5) K2CO3→ K2O + CO2 700℃ (6) CO2 + C →2CO (7) K2CO3 + 2C → 2K + 3CO 700℃ (8) C + K2O →2K + CO 700℃ (9) Form: 400℃ Consumed: 800℃ Consumed: 600℃ Reaction equations Dehydrate：400 ℃ Main activation mechanisms 1.Etching the carbon framework by the redox reactions between various potassium compounds as chemical activating reagents with carbon as shown in eqn (5), (8) and (9), called chemical activation, is responsible for generating the pore network J. Mater. Chem., 2012, 22, 23710–23725 6KOH + 2C →2K + 3H2 + 2K2CO3 (5) K2CO3 + 2C → 2K + 3CO (8) C + K2O →2K + CO (9) Main activation mechanisms 2.The formation of H2O (eqn (1)) and CO2 (eqn (3) and (6)) in the activation system positively contributes to the further development of the porosity through the gasification of carbon, namely physical activation (eqn (2) and (7)) J. Mater. Chem., 2012, 22, 23710–23725 2KOH →K2O + H2O (1) CO + H2O→ CO2 + H2 (3) K2CO3→ K2O + CO2 (6) C + H2O →CO + H2 (2) C + CO2 →2CO (7) Main activation mechanisms 3. The as-prepared metallic K (eqn (5), (8) and (9)), efficiently intercalating into the carbon lattices of the carbon matrix during the activation, results in the expansion of the carbon lattices. J. Mater. Chem., 2012, 22, 23710–23725 6KOH + 2C →2K + 3H2 + 2K2CO3 (5) K2CO3 + 2C → 2K + 3CO (8) C + K2O →2K + CO (9) CNTs KOH 粉末 800℃ 10℃/min