第六章 丙烷催化脱氢反应宏观动力学模型_张海娟.pdfVIP

1464 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012 31 7 113001 580640 0.1 MPh1 Pt-Sn 78.4 kJ/mol Pt-Sn TQ 203.2 A 100066132012 Macro kinetics of catalytic dehydrogenation of propane on platinum-stannum catalyst ZHANG HaijuanLI Jianghong ZHANG ShudongWANG ZhenyuZHANG Xiwen Fushun Research Institute of Petroleum and PetrochemicalsSINOPECFushun 113001LiaoningChina Abstract The experiment of catalytic dehydrogenation of propane on platinum-stannum catalyst was performed with integral fixed-bed reactorunder the reaction conditions of temperature of 580 1 640 pressure of 0.1 MPa and space velocity of 1000 6000 h . The rate equation on macro kinetics of catalytic dehydrogenation of propane was obtained. Through fitting experimental resultsthe parameters of macro kinetic were determined by the method of multiple liner regression. The activation energy of dehydrogenation of propane reaction was about 78.4 kJ/mol. The results of statistic test on macro kinetics model showed that the rate equation was rational and reliable Key words Pt-Sn catalyst propane dehydrogenation propylene macro kinetics model 1 1.1 [1-2]C3 C4 99.9% 99.99% C3 C4 Pt-Sn Pt Sn 1%2% Pt-Sn Cr-Al 1.2 Pt-Sn 10 mm×500