学科文献信息[006]详解.docVIP

学科文献信息 化工专题（ScienceDirect数据库） 第期 （总期） 2016年月日 （请把光标放在文献题名上，按住Crtl键单击题名可打开文献全文） Dual couples Bi metal depositing and Ag@AgI islanding on BiOI 3D architectures for synergistic bactericidal mechanism of燛. coliunder visible light Pages 1-10 Shangbo Ning, Huaxiang Lin, Yuecong Tong, Xiaoyan Zhang, Qianying Lin, Yiqiu Zhang, Jinlin Long, Xuxu Wang Abstract Ag@AgI/Bi-BiOI (AABB) three-dimentional (3D) nanoarchitectures, synthesized by solvothermal reaction and photoreduction method, were used as high杄ffective visible light driven (VLD) photocatalysts for the inactivation of Escherichia coli K?2 (E. coli燢? 12) and were characterized by TEM, SEM, XRD, BET, XPS and DRS. The prepared 30%AABB exhibited the best bacteria disinfection efficiency, and the quantity of viable bacteria could almost inactivate after being illuminated for 18爉in. The enhanced photocatalytic performance can be attributed to the improved separation efficiency of the photogenerated electron–hole pairs because of its multivariant nanoarchitectures with simultaneous electron transfers (Bi?→?BiOICBM?→?Ag?→?AgIVBM). Furthermore, the SEM technology was applied to certify the photocatalytically lethal effect to燛. coli燢?2 and the rupture of bacterial membranes. In this work, the antibacterial mechanism was studied by employing Photoluminescence (PL), Photoelectrochemical Techniques, Electron Spin Resonance (ESR), and scavengers of different reactive species, revealing the pivotal roles of h+, e?, and?O2??in the photocatalytic process. This study indicated that the fabricated AABB photocatalysts could be potentially utilized to disinfect bacteri