共价有机框架材料制备与应用的研究进展.pdfVIP

Vo l. 33 No. 1 广东工业大学学报 第 33 苍第 l 期 2016 年 l 月 Journal of Guangdong University of Technology January 2016 doi: 10. 3969/j. issn. 1 ∞7-7162.2016.01.001 共价有机框架材料制备与应用的研究进展 郭建维，姜文告1]，傅淑琴，李雄 (广东了.业大学轻t化工学院，广东广州 510∞6) 摘要:共价有机框架(COFs) 材料是由各种有机构筑基元通过可逆共价键连接而成的高比表面积晶形有机多孔材 料. COFs 材料以其结构规整、孔道均-、密度低、热稳定性和化学稳定性好等优点，而引起人们的关注-本文介绍了 COFs 材料的基本概念并综述了其构筑基元、构建方式和制备方法，以及 COFs 材料在气体储存、催化、光电等方面 的应用，展望了 COFs 材料在这些领域的研究发展趋势. 关键词:共价有机框架材料;构筑基元;构建方式;合成;应用 中图分类号: TQ311 文献标志码:A 文章编号: 1 ∞7-7162{ 2016) 01-仪lOl-11 Progress of Synthesis and Application of Covalent Organic Frameworks Guo Jian-wei , Jiang Wen-zhao , Fu Shu叮in ， Li Xiong (School of Chemical Engineering and Light Indust町， Guangdong University of Technology , Guangzhou 5JOω6 ， China) Abstract: Covalent organic frameworks (COFs) are a class of crγstalline porous polymers that allow the atomically precise integration of organic uníts to create predesigned skeletons and nano-pores. Sínce the seminal work of Yaghi on covalent organic frameworks , this subject has attracted extensive interest not on- ly from chemists science and organic synthesis , but also from various researchers in the fields of gas storage , heterogeneous catalysis , semi-conduction and photoconduction. This review describes the build- ing blocks of COFs and synthetic methods. The applications are also studied and evaluated. Concerning COFs for future research , some suggestions are proposed and conclusions are given. Key words: covalent organic frameworks j building blocks j building mode j synthesis j application 有机多孔材料是一种由相互贯通或者封闭的纳 Yaghi 等[3 J 运用框架化学( Reticuler Chemistry) [叫