完全液相法中Cu源对Cu-Zn-Al催化剂结构及性能的影响.pdfVIP

第44 卷第 10 期 燃料化学学报 Vo l. 44 No.10 2016 年 10 月 Journal of Fuel Chemistry and Technology Oct. 2016 文章编号: 0253-2409(2016) 1O-1240-D9 完全液相法中 Cu 源对 Cu-Zn-Al 催化剂结构及性能的影晌 张小雨，黄伟\高志华\张琳，时培祥，边仲凯 (太原理工大学煤科学与技术教育部和山西省重点实验室，山西太原 03∞24) 摘 要:采用完全液相法，分别以拧橡酸铜、硝酸铜、乙酸铜为 Cu 源制备了三种 Cu-Zn-Al 浆状催化剂，考察了不同铜源对催 化剂催化合成气制二甲酷性能的影响，利用双D、 H -TPR、阳3 哑D、 BET、XPS 和四M 等技术对催化剂进行了表征。结果表 2 明，铜源对催化剂织构形貌及性能影响显著，用拧撵酸铜为铜源制备的催化剂铜物种分散性最好，铜物种与其他组分间相互 作用强，可还原物质的量多，同时催化剂表面弱酸量与强酸量的比较高，催化剂的甲醇脱水能力提升，三种催化剂中拧橡酸铜 催化剂性能最好，CO 转化率为63.4% ，二甲隧选择性为66.0% 。 关键词:完全液相法j Cu-Zn-Al催化剂;二甲隧;拧橡酸铜;乙酸铜 中固分类号: 0643 文献标识码:A Effect of the source of Cu on the structure and performance of Cu-Zn-Al catalysts prep町ed by complete liquid-phase technology ZHANG Xiao-yu , HUANG Wei , GAO Zhi-hu矿， ZHANG Lin , SHI Pei-xiang , BIAN Zhong-kai ( Key lAboratory 01 Coal Science and Technology 01 Ministry 01 Education and Shanxi Province , Taiyωn University 01 Technology , Ta抄uan 03∞24 ， China) Abs位act: Three kinds of Cu-Zn-Al slurry catalysts were prepared respectively with copper citrate , copper nitrate and copper acetate as 由e source of copper by complete liquid-phase technology. The effects of different sources of copper on the catalytic performance of dimethyl ether synthesis from syngas were investigated. The catalysts were characterized by XRD , H2 - TPR , NH3 - TPD , BET , XPS and TEM. The results indicated 由at the texture mo甲hology and catalytic performance of the catalysts varied significantly. The catalyst prepared with copper citrate showed the best dispersion of Cu species in the catalyst and the largest 缸nount of reducable substance. Meanwhile , the Cu species have 恼。ngest inter