不同pH条件下PBS-PPS的降解性能研究.pdfVIP

现代食品科技 Modern Food Science and Technology 2014, Vol.30, No.2 不同pH 条件下PBS-PPS 的降解性能研究 康宗华，王昌禄 （食品营养与安全教育部重点实验室，天津科技大学食品工程与生物技术学院，天津300457） 摘要：从质量损失率、表面结构形态变化和结晶形态变化等方面，研究了PBS-PPS 嵌段聚酯在不同pH 条件下的水解情况。结 果表明，随着 PBS-PPS 嵌段聚酯中 PPS 链段的增加，材料的降解率提高，不同pH 条件下材料降解率由高到低排序为：碱性环境 （PBS-PPS 嵌段聚酯（PBS 与PPS 的质量比为10:3）在10 周内降解率为46.15% ）酸性环境（33.45%） 中性环境（11.46%）；聚酯 膜的降解从薄膜表面开始，整个过程是一个由外及内逐步深入的过程，并且优先降解无定形区； PPS 的引入阻碍了PBS 的结晶，随 着PPS 链段的增加，材料的结晶半径减小。初步探讨了PBS-PPS 嵌段聚酯在不同pH 环境下的水解机理，实验结论与机理相符。在 碱性环境下，PBS-PPS 嵌段聚酯能够完全水解，在酸性与中性环境中，酯键水解的同时也伴随着其可逆反应的进行。 关键词：生物降解材料；聚酯；降解率 文章篇号：1673-9078(2014)2-95-99 Degradation Property of Block Polyester PBS- PPS under Different pH Conditions KANG Zong-hua, WANG Chang-lu (Key Laboratory of Food Nutrition and Safety, Ministry of Education, Tianjin University of Science Technology , Tianjin 300457, China) Abstract: Hydrolysis behavior of block polyester PBS- PPS under different p H conditions was studied. The degradability, surface morphology and crystal morphology of the copolymer before and after degradation were also discussed, which demonstrated that with the increasing amount of PPS segments in PBS - PPS block polyester, the material degradation rate increased. The degradation rate under different p H conditions was as follows : alkali environment (46.15%) acid environment (33.45%) neutral environment (11.46%). The degradation process of polyester film started from the membrane surface and was prior to degrade amorphous region. With the increasing of PPS segments, the crystallization radius of the material was reduced, which mainly due to the introduction of PPS hindered the crystallization of PBS. The experiment result of hydrolysis under different