石墨热解碳纳米晶薄膜电极的电化学传感肼.pdfVIP

Sensors and Actuators B 160 (2011) 121–128 Contents lists available at ScienceDirect Sensors and Actuators B: Chemical j o u rn a l h o me p ag e: w w w. elsev /locate/snb Nanocrystalline graphite-like pyrolytic carbon film electrode for electrochemical sensing of hydrazine Mojtaba Hadi a , Ahmad Rouhollahi a,b,∗ , Mohammad Yousefi c a Department of Chemistry, Faculty of Sciences, K.N. Toosi University of Technology, Tehran, Iran b Department of Chemistry, York University, 4700 Keele St., Toronto, ON, Canada M3J 1P3 c Department of Petrochemicals, Iran Polymer and Petrochemical Institute, Tehran, Iran a r t i c l e i n f o a b s t r a c t Article history: Pyrolytic carbon film (PCF) electrode fabricated by a non-catalytic chemical vapor deposition (CVD) Received 5 May 2011 process was used as an electrochemical sensor for the detection of hydrazine. The electrode response Received in revised form 4 July 2011 was found to be electrocatalytic producing a reduction in the overpotential compared to other unmod- Accepted 12 July 2011 ified carbon-based electrodes such as glassy carbon (GC), basal-plane pyrolytic graphite (BPPG), and Available online 21 July 2011 edge-plane pyrolytic graphite (EPPG) electrodes. The overall number of electrons involved in the electro- oxidation of hydrazine, the number of electrons involved in the rate-determining step, and diffusion Keywords: