杂化材料中有机小分子形态对阻尼性能影响.PDFVIP

23 Effect of the State of Organic Small Molecule in Hybrid Materials on Damping Properties , , ( , 201 20) DING Xin-bo , ZHAN G Hui-ping , YAN Xiong ( The Key Lab of Textile and Technology, Ministry of Education, College of T extiles, Donghua University, Shanghai 201 20, China) : ( DMA) ( DSC) ( CPE) 2, 2- -(4-- - ) ( EBP) (2--3--5 )-( ZKF) CPE/ EBP DMA , 5% EBP , CPE/ EBP , CPE CPE/ EBP , CPE EBP , CPE/ ZKF , ZKF DSC , CPE/ ZKF ZKF EBP ZKF : ; ; ; : TB332 : A : 1001-4381(2008) 04-0023-04 Abstract : T he damping properties of organic hybrids consisting of chlorinated polyethylene ( CPE) , 2, 2c-methylene-bis-( -tert- buty-l 4-ethy-l phenol) ( EBP) , and 2c-methylene-bis-( 4-methy-l -cyclohexyl- phenol) ( ZKF) have been investigated by dynamic mechanical analysis ( DMA) and differential scan- ning calorimetry ( DSC) 1 T he dynamic mechanical thermal properties of CPE/ EBP hybrid materials show that all CPE/ EBP hybrid samples clearly exhibit tw o significant peaks except the CPE/ EBP w ith 5% mass fraction, and a novel relaxation peak appears above the glass-transition temperature of CPE, implying that there is a CPE-rich matrix phase and an EBP-rich domain co-existed in CPE/ EBP hy- brids1 How ever, there is only one loss peak for all the samples of the CPE/ ZKF hybrids and the height of the loss peak increases drastically w ith the increased content of ZKF1 From the DSC meas- urements, w e find that all of the CPE/ ZKF hybrid samples are almost in an amorphous state and has only one phase1 T hese may imply that the dispersal state of the organic filler in polymer matrix