赤铁矿对砷的吸附解吸及氧化特征.pdf

DO I :10.13671/j .hjkxxb.2008.08.023 28 8 　　　　　 Vo.l28, No.8 2008 8 　ActaScientiaeCircumstantiae Aug., 2008 , , , .2008.[ J]., 28(8):16 12-1617 WangQ, BuJC, WeiSQ, eta.l2008.Characteristicsoisothermaladsorptionanddesorption, andoxidationoAs(Ⅲ)iononahematitesurace[ J]. ActaScientiaeCircumstantiae, 28(8):16 12-16 17 1, 2 1 1, ＊ 2 王强 ,卜锦春,魏世强 ,黄玉明 1.西南大学资源环境学院, 重庆市农业资源与环境研究重点实验室, 重庆 4007 16 2.西南大学化学化工学院, 重庆 4007 15 :2007 -07-04　　　:2007 -12 -26　　　:2008-05 -26 :, (α-FeO), 、 pH 2 3 2 ., Langmuir (R=0.9939 );, As(V) (), ;35℃、 25℃, . As(Ⅲ), pH8, pH, pH=8 , pH; pH 6.0 , pH As(Ⅲ)、 , pH 6.0 , pH As(Ⅲ), pH=6.0 . :;;; :0253 -2468 (2008)08 -1612 -06　　　:X13 1.2　　　:A Characteristicso isothermaladsorptionanddesorption, andoxidationoAs (Ⅲ)iononahematitesurace 1, 2 1 1, ＊ 2 WANGQiang, BUJinchun, WEIShiqiang, HUANGYuming 1.CollegeoResourcesandEnvironmen,tSouthwestUniversity, KeyLaboratoryoAgriculturalResourcesandEnvironmen,tChongqing4007 16 2.CollegeoChemistryandChemicalEngineeringoSouthwestUniversit,yChongqing4007 15 Received4 July2007;　　　receivedinrevisedorm26 December2007;　　　accepted26 May2008 Abstrac:tArseniccanbeadsorbedintosoilsbyreactionwithiron-containingmineralssuchashematit.eTheAs(Ⅲ)adsorptionanddesorptionisotherms onthehematite(α-FeO)suraceweremeasuredandtheoxidationprocesswasinvestigated, asaunctionopHandtemperatur.eTheLangmuir 2 3 equationsdescribetherelationshipoadsorptionamounttotheoriginalconcentrationoAs(Ⅲ )well(p 0.05 ).TheconcentrationsoAs(V) (oxidized)inthesolutionincreasedbuttheoxidationratesdecreasedastheinitialAs(Ⅲ)concentrationincreased.Temperatureisanmiportantactor inluen