超临界流体CO2.docVIP

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超临界流体CO2

超临界流体CO2 SupercriticalCO2fractionationofbio-oilproducedfromwheat–hemlockbiomass SatyanarayanNaik,VaibhavV.Goud,PrasantK.Rout,AjayK.Dalai* CatalysisandChemicalEngineeringLaboratories,DepartmentofChemicalEngineering,UniversityofSaskatchewan,Saskatoon,SK,CanadaS7N5A9 articleinfoabstract Thebiomassi.e.wheat–hemlockusedinthisstudywas?rstcharacterizedforitscomposition.Thephys-icalandchemicalcharacterizationofbiomasswasestimatedusingproximateanalysis,calori?cvalue,crystallinity,devolatilizationbehaviour,ultimateanalysis,ICP-MSofash,FT-IR,XRD,CHNS,andHPLCanalysis.Forcommercialpurposethesamebiomasswasusedforconversiontobio-oilbyfastpyrolysisprocess.Therefore,inordertoinvestigateitscomposition,thebio-oilwasalsocharacterizedusingprox-imateanalysis,calori?cvalue,whereasthechemicalcompositionofthebio-oilwasestimatedusingCHNS,1HNMR,GC-FIDandGC/MS.Thebio-oilobtainedfromwheat–hemlockbiomasswassuppliedbyAdvancedBiore?neryCo.andaftertheanalysis,itscompositionhasbeendetermined.Itcontainsamixtureofhydrocarbons,pyranoids,furanoids,benzenoidsandfattyacids/alcoholswith45%ofwater,whichformsazeotropewithorganicpolarcompounds.ThesupercriticalCO2(SC-CO2)isanadvancedmethodforselectiveextractionofvaluablechemicalsfrombio-oilwithoutsolventresidue.Theorganicfractionofthebio-oilwasisolatedbySC-CO2.ItwasobservedthatSC-CO2fractionscollectedat10and25MPapressurewereenrichedwithfuranoids,pyranoidsandbezenoids.Similarlythebio-oilwasalsofractionatedbyconventionalcolumnchromatographicmethodandtheyieldsandchemicalcompo-sitionswerecomparedwithfractionatedbio-oilobtainedusingSC-CO2. ó2010PublishedbyElsevierLtd. Articlehistory: Received9May2009 Receivedinrevisedform8April2010Accepted8April2010 Availableonline20May2010Keywords: Wheat–hemlockbiomassBio-oil SupercriticalCO2 ColumnchromatographyAnalysis 1.Introduction Alternativeandrenewableenergyresourceshaverecentlybe-comeahighpriorityformanycountriesandwillplayalargeroleinthechemicalindustryinthenearfuture.Theserenewableen-ergyresourceshavebecomepopulari

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