具高效能紫外光遮蔽性之有机-无机奈米复合薄膜 ... - 淡江大学机构典藏.pdfVIP

Abstract In this investigation, sol-gel method was employed to synthesis the polyurethane/titania nanocomposites and the chelating agents were added to resolve the drawbacks of the UV-shielding film nowadays such as poor and limited range of UV absorption, photodegradation and light interference effect. PU with hydroxyl side chains was synthesized to incorporate the coupling agent in order to enhance the dispersion of titania in the polymer matrix. The AcEA chelated hybrid materials do perform high and broad UV absorption observed in the experimental results, the thicker the film the higher the UV-shielding performance. With the film thickness 5μm and titania 20 wt%, ultraviolet can be cut off perfectly and the transmittance of the visible light is over 95 %. By adding 5 wt% of coupling agent, 50 wt% of titania can be incorporated in the PU matrix designed. The light interference would be low because the maximum reflect index of the hybrid materials is 1.68 which is close to that of the glass substrate. Keywords: polyurethane/titania nanocomposites, coordination compound, UV-Shielding 一、中文摘要 本研究利用溶膠-凝膠法製備聚胺基甲酸酯/ 二氧化鈦抗紫外線奈米混成材 料，藉由添加鈦螯合物的方式改善一般抗紫外線薄膜吸收範圍狹窄、吸收效果不 佳、高光催化能力及嚴重的光干擾等問題。為改善二氧化鈦的分散性與增加添加 量，本研究合成側鏈具有 OH官能基的聚胺基甲酸酯高分子，並加入偶合劑使其 一端與聚胺基甲酸酯的 OH官能基反應，另一端與螯合物反應，使得有機高分子 與無機螯合物之間能形成化學鍵结，增加無機物的分散性與添加量。以乙醯丙酮 加乙醇胺系統(AcEA)製作之混成材料具有大範圍、高強度紫外光吸收，隨著膜 厚增加吸收峰會有紅移現象且吸收強度也會隨之增強。無機添加量 20 wt%及膜 厚 5 μm即可 100%遮蔽紫外光且可