中国甲酸钠法制保险粉技术的发展及展望.pdfVIP

无机盐工业 第 39 卷第 6 期 4 INORGANIC CHEMICALS INDUSTRY 2007 年6 月 中国甲酸纳法制保险粉技术的发展及展望 黄力群 (湘障大学化工学院，湖南湘潭 411105) 摘 要:对近年来中国在阳酸铀法制保险粉技术方面取得的创新成果，以及保险粉制造业跃居世界首强的情 况，作了全顶的总结和阐述。创新成果主要有:用甲酸铺、二氧化晓和焦亚硫酸纳生产保险粉;甲酸饷和焦亚硫酸 饷以晶粒状态加入反应釜;将一种能与硫代硫酸盐反应的有机物加入到母液中;母攘的循环利用率达到 60% 问 80% ;保险粉的产量去成倍增加;甲酸铀的利用率提高~73%等。同时深入分析了将上述有机物加入到母液中所带 来的安全风险和环境污染问题，提出了中回保险粉企业需要在安全技术、环保技术和监控技术等方面作相应改进 的具体建议。 关键词:甲酸铀;保险粉;二氧化硫;焦亚疏酸销 中图分提号:TQ13l. 12 文献标识码:A 文章编号:1ω6 币 4990 (2007 )06 由 α泊4 … 03 Development and prospect on rongalite technique by sodium formate process in China Huang Liqun ( College of ChRmical Engineering ,Xiangtan Univers时， Xiangtαn 411105 ,Chinα) Abstract: 四e innovative results achieved ìn the tenn目。f rongalìte technìque by sodìum fonnate process in China ìn re- cent years as well a自 the situation that Chinese rongalite manufacturing industry leapìng into the first rank of the world were summarÌzed and introduced comprehensively in this paper. The innovative result吕 included :production of rongalite from sodi嗣 um fonnate ,sulfur dioxìde and sodium pyrosulfite j additíon of sodium fonnate and sodìum pyros幽te to reactors in the fonn of crystal grain j addition of an organic compound which is able to react wi由 thiosulfate 10 mother liquorj achievement of 60% - 80% in recycle ratio of mother liquorj double incr，日ment of the yield of sodium dithionitejand improvement to 73% in utilízation ratio of sodium fonnate. Meanwhile ,the new problems of safety risk and environmental