SOFC中低浓度干甲烷在NiYSZ阳极上的反应-高校化学工程学报.PDF

21 2 No.2 Vol.21 2007 4 Journal of Chemical Engineering of Chinese Universities Apr . 2007 1003-9015(2007)02-0286-06 SOFC Ni/YSZ 1 1 2 , , · (1. , 116012; 2. , 030-0113) (SOFC) Ni/YSZ YSZ LSM CO TM911.44 A Reactions of Low Concentration Dry Methane on Ni/YSZ Anode of SOFC 1 1 2 YOU Hong-xin , DING Xin-wei , ABULITI·Abudula (1. Chemical Engineering College, Dalian University of Technology, Dalian 116012, China; 2. New Energy Technology Research Division, Aomori Industrial Research Center, Aomori 030-0113, Japan) Abstract: The recent trend in solid oxide fuel cell (SOFC) concerns the direct use of methane or natural gas. It is very important to know the chemical and electrochemical reactions of methane over the anode of SOFC. The reactions of low concentration dry methane on SOFC with Ni/YSZ anode, YSZ electrolyte and LSM cathode were studied. Using 8% (mol) YSZ plates as electrolyte, the fuel cells with different anode thickness were made by slurry coating process. The gas composition at the anode outlet was measured by on-line chromatogram at different current density for SOFCs with different methane concentration, operating temperature and electrolyte thickness. Based on the production rate of CO, H and CO , the varieties of methane 2 2 reaction at anode were analyzed. Consumption of oxygen and shifted electrons were calc