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第九章 电解过程化学火用传递分析示例.pdf

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2005 68 w021 ( 163318) - A Method of Chemical Exergy Transfer Analysis in Electrolysis Zhu Yuanhai, Wang Baohui, Liu Yang, Xiang Xinyao (Petroleum Chemical Engineering Department, Daqing Petroleum Institute, Daqing 163318) Abstract The exergy transfer and dissipation characteristics in electrons and ions transport, in diffusion and reaction of ions on electrode surface are analysed with chemical exergy transfer method. Generalized expressions of polarization overpotentials and Joule-lenz’ law related to electrical exergy disspation are obtained naturally in the mathematical treatment. It is illustrated in the paper that exergy transfer analyisis is a kind of valuable dynamic method in exergy analysis. Key words Chemical exergy tranfer, Efficiency of exergy, Process rate (exergy)(available energy) [1] [2] [3] Soma 80 [4,5] [6~8] 1 42 E-mail: yuanhaizhu@163.com 973 (G2000026307) 2004-02-21 2004-08-11 2005 68

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