叶黄素的热解产物分析.pdfVIP

叶黄素的热解产物分析 侯 英，徐济仓，王保兴，杨 燕，杨 勇，王 玉，刘 静 云南瑞升烟草技术(集团)有限公司，昆明市高新技术产业开发区科医路41号 650106 关键词：叶黄素；烟草；热解；气相色谱 一质谱分析；固相微萃取 摘要：为研究叶黄素对卷烟燃吸品质的影响，分别在300、600、900℃和氮气、10％氧气+90％ 氮气、大气环境中进行了叶黄素热解试验，热解产物经固相微萃取后进行GC／MS分析，并用叶 黄素进行了卷烟加香试验。结果表明：①在所试验的温度和氛围中，叶黄素的裂解产物主要是 甲苯、对一二甲苯、1，2一二氢一1，1，6一三甲基一萘和2，7一二甲基萘等，另外还有少量的氧 化异佛尔酮、巨豆三烯酮、醛和烯烃类物质等；②叶黄素裂解产物的种类和相对含量都随着裂 解温度的变化而变化，而裂解氛围则影响不大；( 添加叶黄素的卷烟烟气香气略增加，但其杂 气、刺激性都明显增大，余味变差。因此，添加叶黄素不利于卷烟抽吸品质的提高。 中图分类号：TS264．3 文献标识码：B 文章编号：1002—0861(2007)12—0027—06 Analysis of Pyrolytic Products of Lutein HOU YING，XU JI-CANG，WANG BAO-XING，YANG YAN，YANG YONG，WANG YU，and LIU儿NG Yunnan Reascend Tobacco Technology(Group)Co．，Ltd．，Kunming 650106，China Keywords：Lutein；Tobacco；Pyrolysis； Gas chromatography／mass spectrometry；Solid phase microextraction Abstract：To investigate the effect of lutein on the smoking quality of cigarettes，the lutein was pyrolysed in various surroundings(N2，10％ O2+90％ N2，and air)at 300℃，600℃ and 900℃ ，respectively．The pyrolytic products adsorbed by solid phase microextraction were analyzed with gas chromatography／mass spectrometry，and lutein was applied to cigarettes as a flavor．The results showed that：1)in all pyrolytic environments and temperatures，the major components of pyrolytic products were tolune，P-xylene，1，2一dihydro一1，1，6一trimethylnaphthalene，2，7一 ★烟草科技 0 ∞^^0∞^ie目^o印 eclI目010gy★ ★烟草化学 0 ∞^^0 lIblllisl_《★ dimethylnaphthalene， etc．， and the minor components were isophorone， megastigmatrienone， 0 aldehydes，alkenes，etc，；2)the kind and relative content of pyrolytic products changed with the 0 change of temperatures，while the influence of environment was negligible；3)lutein adding would 笠 第 enhance the arom