4-甲基苯亚磺酸钠的合成吴建一.pdf

276 精 细 化 工 V ol. 27, N o. 6 2 0 1 0 6 FINE CHEM ICALS Jun e 2 0 1 0 4- 1, 2 2 1 1 吴建一 , 邹 玲 , 缪程平 , 宗乾收 ( 1. , 3 14001; 2. , 213164) : 4- 4-, , 4-, 10% pH: n ( 4-) Bn () = 1B1109, 85 e , 1 h, m () /m ( 4-) = 10, pH = 716, 89% : 4-; 4-; ; : TQ 247. 5; O 625. 75 : A : 100 3- 52 14 ( 20 10) 06- 0614- 04 Synthesis of Sodium 4-Methylbenzene Sulfinate 1, 2 2 1 1 WU Jian-y i , ZOU L ing , M IAO Cheng-ping , ZONG Q ian-shou ( 1. Colleg e of B iology and Chem ical E ng ineer ing and C lean Chem ical P rocess L a boratory of J iax ing C ity, J iax ing Un iv er sity, J iax ing 314001, Zhej iang, Ch ina 2. D ep ar tm ent of Chem ical E ng ineer ing, J iang su P o ly tech n ic Un iv ersity, Changzhou 213 164, J iang su, Ch ina) Abstract: The synthesis o f sod ium 4-m ethy lbenzene sulfinate w as investiga ted by u sing the sodium sulfite deox id izat ion process from the starting m ater ia l 4-m ethy lbenzene su lfony l chloride, and the contents o f product w ere analyzed by UV-spectropho tom etr ic m ethod. T he aqueou s sodium sulfite wh ich used as a substrate w as added to d ichlorom ethane so lution conta in ing 4-m ethy lbenzene su lfony l ch lo ride, at the sam e tmi e, the pH w as con tro lled by adding dropw ise 10% sodium hydrox ide so lu tion in the reaction process. T he optmi un reaction conditions