表目录 - 国立高雄应用科技大学化学工程与材料工程系.docVIP

摘要 本研究探討陣列式二氧化鈦奈米管結構應用在染料敏化太陽能電池上之研究，主要研究項目有：（1）利用陽極氧化法（Anodization Method）製備陣列式二氧化鈦奈米管、（2）利用浸漬塗佈法（Dip Coating）的方式在FTO導電玻璃上成長Pt薄膜電極， 並探討在不同浸漬時間下對染料敏化太陽能電池的影響。 由XRD分析發現，製作出來的陣列式二氧化鈦奈米管在500℃煅燒下具有最強的銳鈦礦結晶相位（2θ = 25.6°（101）），此晶相有利於染料電子的轉移。藉由UV-Vis分析發現，對應電極隨浸漬時間增加，整體的穿透效果略有降低。染料是選用N-719，其有如植物中葉綠素的原理一樣，能夠幫助二氧化鈦的光激發波段提昇至可見區，吸附染料後的二氧化鈦會有較強的吸能力。 量測的結果發現，浸漬塗佈10分鐘作出的對應電極其效率優於60分鐘所作出的對應電極，且將陽極浸泡於TiCl4溶液，TiCl4的加入會沉積在二氧化鈦薄膜電極材料的孔隙交接處，而交接處的增加會有助於加速電子的傳遞，減少再結合反應的發生。 Abstract In this study, we explore the application of titanium dioxide nanotube arrays in dye-snesitized solar cells. The mainly of the research project are :（1）Preparation of TiO2 nanotube arrays by anodization method.（2）Fabrication of the platinum thin film electrode grow in the FTO conducting glass by dip coating and discussed the different time effect on dye-snesitized solar cells. By the XRD analysis, we found out we have produced TiO2 nanotube arrays under calcination at 500 ℃ with the strongest anatase crystalline phase (2θ = 25.6 ° (101)), this crystalline phase is conducive to electron transfer. By UV-Vis analysis showed that the counter electrode overall penetration slightly lower with increasing immersion time. In this study, the dye was selected N-719, its like the principle of chlorophyll in plants and can help to TiO2 excitation band area upgrade to the visible light, after the dye adsorption of titanium dioxide would have a better absorptive capacity. The efficient measurement results showed that 10 minutes dip coating of the counter electrode is superior to 60 minutes. The photoanode was immersed in the TiCl4 solution, because TiCl4 accession will be deposited in TiO2 thin film electrode material pore junction , while the junction of the increase will help to accelerate the electron transfer and reducing recombination of the reaction. 目錄 摘要 I 英文摘要 II 致謝 IV 目錄 V 圖目錄 VIII 表目錄 X 第一章 緒論 1 1.1 前言 1 1.2 太陽能電池簡介 4 1.3 研究動機 5 第二章 文獻回顧 7 2.1 二氧化鈦簡介 7 2.2 陽極氧化法（Anodization Method） 14 2.2.1