光生物双降解薄膜的降解性能研究.pdfVIP

，料 2007 年 36 卷第4 期 光/生物f.J.降解薄膜的降解性能研究 光/生物双降解薄膜的降解性能研究掌 齐字虹，陈建华 (北京燕山石化塑料分公司，北京 102500) 摘要:研究了由光敏剂硬脂酸铁和抗孰剂 1076 组成的光降解体系的光/生物双降解来乙烯薄膜在 紫外灯辐照下的分子堂、脆化期、诱导期、生物降解性能等的变化规律，并用红外光谱仪表征了塑料膜的 化学结构变化，用电子显微镜观察了薄膜表面的微生物生长丰度。结果表明:硬脂酸铁具有促进光降解 和抑制交联的双重作用;抗氧剂 1076 具有较强的抑制光降解作用;硬脂酸铁和抗氧剂 1076 对诱导期的 影响均比脆化期强;由它们组成的光降解体革经过光照后具有较强的生物降解性能。 关键诩:光/生物双降解薄膜;复合光降解剂;分子楚:诱导期;脆化期;生物降解 中图分类号:TQ325.1 ， TQ320.721 文献标识码:A 文章编号:1001 喃 9456 (2007 )04 币。054 -05 Degradability of Photo.Biodegradable Films 。1 Yu嗣hong ， CHEN Jian-hua (Plastic Branch of BYPC Co. ,Ltd ,Beijing 102500 ,China) Abstract :The molecular weight ,induction period ,embritÙement time and biodegradation of photo翩biode翩 gradable PE films with various concentrations Fe( St) 3 and antioxidantl076 were studied. The structures of the films were ohserved hy FT-IR and the growth scale of microorganism on the films was observed by electron microscope. The results indicated that Fe ( St) 3 could accelerate photo嗣degradation and restraÎn crosslinking; antioxidantl076 could re8train photo唰degradation ; F e ( St) 3 and antioxidant1076 a180 were more effective on the induètion. þeriod than the embrittlement time; photo-biodegradable film8 had obviously biodegradable performance after illumination. Key words: photo唰hiodegradable films; photo瞩目ensitizer system; molecular weight; induction period; embrittlement time; biodegradation 地膜技术的推广和应用对我国农业增产增收起到 所组成的光降解体系下的光降解规律和生物降解牲 了巨大的作用，但过学地膜未及时处理易说人土壤，长 自旨，为生产可时控的光/生物降解塑料提供了…定的技 期积累会造成农丽的严意、污染[110 解决这一问题可