全生物基脂肪芳香族不饱和共聚酯的合成及其性能研究.pdfVIP

石油化工 .330. PEτROCHEMICAL TECHNOLOGY 2012 年第41 卷第3 期 E雪地f七二新材料 全生物基脂肪/芳香族不饱和共聚醋的合成 及其性能研究 任静娇，东为富，施冬健，倪忠斌，陈明清 (江南大学化学与材料工程学院，江苏元锡 214122 ) [摘要]以生物墓3 ，年二经基肉佳酸 (DHCA) 和M麻油酸 (RA) 为单体，采用熔融缩聚法合成了二者的共聚物PDH及 DHCA的均聚物PDo 采用FTIR、 DSC、 HNMR、 GPC和荧光分析等方法对PDH和PD进行了表征。实验结果表明， PDH中 DHCA与RA结构单元的比例与聚合反应时单体加入量 (n (DHCA) : 11 (队) )基本-致，反应体系中灿的加入有利于提 高PDH的相对分子质量，且大于PD的相对分子质量，当n (DHCA) : 11 (RA ) =4 : 3时聚合产物PDH的数均相对分子质量为 4 2.78 X 10 ; 随PDH中柔性链段民A含量的增加， PDH的玻璃化转变温度降低，断裂伸长率增大，降解速率变慢， PDH中DHCA 含量的降低使得分子结构的共辄性整体有所下降。 [关键词} 3， 4-二瓷基肉桂酸:莲麻油酸E 生物基脂肪/芳香族不饱和共聚醋:生物基可降解高分子 [支章编号}JOω- 8144 ( 2012 ) 03 - 0330 - 05 [中图分类号} TQ317.S [文献标识码 JA Synthesis and Properties ofBio-Based AlkyVAromatic Unsalurated co-Polyester RenJingj.脚， Dong Jf告拙， Shi Dongjian , Ni Zhongbin , Chen Mingqing (School of Chemical 姐dMa阳ial Engíne町吨， Jiangnan Univers邸， Wu沮Jiangsu 214122. China) [ Abstract ] Bio-based alkyl/aromatic unsaturated co-polyester(PDH) was s归thesized from 3 , 4-dihydroxycinnamic acid(DHCA) and ricinoleic acid(RA) , and homo-polyester of DHCA(PD) was s归thesized from DHCA through thermal polycondensation. PDH and PD were characterized by means of FTIR , DSC. I H NMR , GPC and iluorescence spec位ophotometer. The results showed that n(DHCA) :. n(RA) in PDH molecular was almost the same as that of the reactants; adding RA in the reaction sys阳n could increase the average relative molecular mass of PDH , which was bigger than 4 由at of PD , and the number average relative molecular mass of PDH was as