镁橄榄石和炭黑为原料合成MgO_SiC_C系复合粉体.pdfVIP

44 12 西 安 交 通 大 学 学 报 Vol. 44 12 2010 12 JOU RNA L OF XIAN JIAOT ONG UNIVERSIT Y Dec. 2010 MgOSiCC , , , , ( , 4300 1, ) : 以湖北宜昌镁橄榄石细粉与炭黑为原料, 分别以4 种质量比混 均匀, 以热固性酚醛树脂作 为结 剂, 在200 MPa 压力下压制成20 mm 20 mm 试样, 置于110 干燥箱中干燥24 h, 然后 在高温管式气氛炉中通入氩气作为保护气氛, 分别在 1 550 1 600 1 650 和 1 700 保温 3 h烧成. 对烧成的试样分别进行X 射线衍射和扫描电镜检测, 结果表明: 原料中Fe2 O3 杂质经高 温烧成后转变为FeSi; 不同试样经不同温度烧成后都含有少量的MgAl2 O4 和SiO2 ; 烧成温度与炭 黑含量是影响MgOSiCC 复 粉体 成的重要控制因素, 当烧成温度为 1 600 , 镁橄榄石细粉 与炭黑原料的质量分数分别为795%205% 和745%255% 时, 能够比较好地 成MgOSiCC 系复 粉体. : 镁橄榄石; MgOSiCC; 碳化硅; 炭黑 : TF0651 : A : 02539 7X( 2010) Synthesizing MgOSiCC Refractory Composite Powder from Forsterite and Carbon Black WEI Yingfeng, DENG Chengji, ZHU Hongxi, ZHANG M eijie, GU Huazhi ( The State Key Laboratory Breeding Base of Refractories and Ceram ics, Wuhan University of Science and T echnology, Wuhan 4300 1, China) Abstract: T he MgOSiCC composite pow ders are prepared using forsterite ( Yichang, Hubei province) and carbon black pow ders as raw materials. Forsterite and carbon black are uniformly mixed in 4 mass ratios w ith phenolic resin as the binder , and then cold pressed into the specimens w ith the size of 20 mm 20 mm. T he samples are dried at 110 for 24 hours, and sintered at 1 550 , 1 600 , 1 650 and 1 700 , respectively, by holding 3 hours in argon atmosphere. Test results for the sintered samples using XRD and SEM show that after high temperature sinte ring, Fe2 O3 is transformed into FeSi, a few MgAl2 O4 and SiO2 phases exist in samples, and that the sintering temperature and the carbon black content are the key factors to affect synthesizing of MgOSiCC composite pow ders. T he MgOSiCC composite pow ders a