第二章氨基酸的离解 性质 合成及应用.pptVIP

2.2 Dissociation Behavior 离解行为 1、 Zwitterion两性离子 Organic salts Amino acids are crystalline solids结晶固体 which usually decompose分解 or melt融化 in the range of 200-350℃, and are poorly soluble in organic solvents. These properties suggest that they are organic salts and the evidence is that they exist in the crystal lattice晶格 as a dipolar ion or zwitterion. That is, the acidic proton from the carboxyl function protonates the amino function on the same molecule. 质子化的氨基、离解状态的羧基 This is not peculiar to amino acids but can instead be representative of any organic salt (i.e., nucleotides; organic mo