顺磁共振法测定气相中OH 自由基的研究 - 环境科学.PDFVIP

1999 11 ENVIRONMENTA L SCIENCE Nov. , 1999 * OH 1 2 2 1 1 潘循皙 　陈士明　严小敏 　董文博 　侯惠奇 ( 1. ; 2. , 200433) (EPR) OH , 4-PO N OH , 4-PO N -OH . 2d , EPR . OH EPR = 1. 45mT = 0. 22mT . O , EPR . N H 2 OH EPR , EPR . , , OH , , . - Determination of Gas phase OH Radical Concentrations Using Electron Paramagnetic Resonance 1 2 2 1 1 Pan Xunxi Chen Shiming Yan Xiaomin Dong Wenbo Hou Huiqi ( 1. Institute of Environmental Science Fudan University Shanghai, , 200433, China 2. Analysis and M easurement Center, Fudan University, Shanghai 200433, China) - Abstract T he paper described the method of detecting gas phase OH using Electron Paramagnetic Resonance (EPR) .Hydroxyl radical w as trapped in a spin trap to form a stable hydroxyl adduct and determined by Electron Paramagnetic Resonance later. 4-PO N w as chosen as the spin trap because it show ed the higher OH trapping ability and the higher stability of spin adduct .T he EPR spectra of OH-adduct remains unchanged w ithout light for tw o days.T he hyperfine coincidence constants, and w ere 1.45mT and 0.22mT respectively. Also it w as N H - show ed that the EPR spectra of OH adduct from atmosphere sampling in Shanghai were in agreement with those obtained from the model experiments. KeywordsEPR,spin trapping,OH radical,gas-phase, atmospheric pollution chemistry. [ 6, 7] , OH OH . [ 1] . EPR OH , OH , OH . . ( , , OH 6