便携式原子吸收测汞仪对气态汞的监测方法的研究与应用.docVIP

便携式原子吸收测汞仪对气态汞的监测方法的研究与应用 陆家骝 吴福全 卢仁杰 梁柱 摘要对某燃煤电厂排气筒中的气态汞进行测定，并与进行同步比对监测，测定结果显示，关键词 气态汞 Research and Application of Gaseous Mercury Monitoring Method Using Portable Atomic Absorption Mercury Analyzer Lu jia－liu; Wu fu－quan; Lu ren－jie; Liang zhu (Suzhou Environmental Monitoring Center, Jiangsu Suzhou 215000) Abstract: The gaseous mercury monitoring become more attention in the air and industrial waste with Mercury pollution in the environment increasing. This paper studied the mercury monitoring method using QM201G portable gaseous mercury analyzer. The paper compared the principle, the process and the performance of gold amalgam mercury enriching analyzing method and direct atomic absorption mercury analyzing method. The results showed that the coefficient determination of standard curve by gold amalgam is more than 0.99. The gaseous mercury concentration (C) of exhaust gas was measured by atomic absorption method. The gaseous mercury concentration (C), the initial atomic absorption energy (N0) and the cutting atomic absorption energy after Mercury vapor (N1) satisfy the formula C = k (logN0 - logN1). And the constant k stabled for 1400 in high concentration of mercury. The vent gaseous mercury were measured by the atomic absorption method of QM201G and the cold atomic absorption spectrophotometric method of environment standard method in a coal-fired power plant in Suzhou. The results showed that the gaseous mercury concentration of two methods in the same order of magnitude. Research has shown that this instrument is suitable for monitoring gaseous mercury of pollution sources. Key words: Gaseous Mercury; Monitoring; Portable Mercury Analyzer; Gold Amalgam; Atomic Absorption 前言 汞在环境中是一种痕量重金属污染物，进入生物体后很难被排出，并会在生物体的作用下转化为甲基汞，产生极强的生物毒性，同时由于生物体内汞的累积作用，汞会沿食物链逐渐向高端富集，最终影响人类的健康。排放到水体中的汞严重污染当地环境，而排放到大气中的元素汞（Hg0）可在区域和全球范围内随着大气环流长距离传输，并沉降到一些远离污染源的地区，导致生物体内汞或甲基汞含量增加，造成不可估量的健康和经济损失。汞成为温室气体和持久性有机物后又一引人关注的全球性化学污染物，汞污染和控制问题成为目前全球环境问题的新热点和前沿研究领域。汞的测定方法很多，如巯基棉富集-冷原子荧光分光光度法测定环境空气中