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Organic Electronics 10 (2009) 1562–1570 Contents lists available at ScienceDirect Organic Electronics journal homepage: www.else /loc ate/orgel A new approach to efficiency enhancement of polymer light-emitting diodes by deposition of anode buffer layers in the presence of additives Hongbin Wu a,*, Jianhua Zou a, Ding An a, Feng Liu a, Wei Yang a, Junbiao Peng a, Alexander Mikhailovsky b,c, Guillermo C. Bazan b,c,*, Yong Cao a a Institute of Polymer Optoelectronic Materials and Devices, Key Lab Specially Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou 510640, People’s Republic of China b Department of Chemistry Biochemistry, Department of Materials, Center for Polymers and Organic Solids, University of California, Santa Barbara, CA 93106, USA c Department of Biochemistry and Materials, Institute for Polymers and Organic Solids, University of California, Santa Barbara, CA 93106, USA a r t i c l e i n f o a b s t r a c t Article history: Here we report a new approach for the preparation of anode buffer layer for efficient poly- Received 10 May 2009 mer light-emitting devices (PLEDs) by using glycerol to modify relative low conductivity Received in revised form 1 September 2009 poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS). This new type of Accepted 3 September 2009 anode buffer layer allows for a 50–90% increase in device performance for green emitting Available online 18 September 2009 phosphorescent PLEDs in terms of luminous effici