Cu2+-钨酸盐-罗丹明6G体系共振散射光谱法测定面粉和茶叶中微量铜.pdfVIP

110 2015， 协11. 36， No.04 ※成分分析 自自融事 2 Cu +_锦酸盐·罗丹明6G体系共振散射光谱法 测定面粉和茶叶中微量铜 邵娅婷，毛智成，王沛霖，陈瑾，曹秋娥* (云南大学化学科学与工程学院，教育部自然资源药物化学重点实验室，云南昆明 白∞91) 摘 要z 利用Cu2+和鸽酸盐形成的铜鹊杂多酸阴离子与罗丹明6G阳离子结合生成离子缔合物的反应，建立一种测 定Cu2+的共振散射光谱法。该反应在聚乙烯醇存在条件下，子589nm波长处产生的共振散射光强度与Cu2+质量浓度 在0.05~ 1. 0 ng/mL范围内有良好的线性关系，线性回归方程为M=4.38+77. 12c (r=0.997 1) ， 方法的仪器检出限 为0.026 ng/mL， 方法简单、快速、灵敏度高，且大量存在的常见离子对Cu2+的测定不干扰，将其用于面粉和茶叶 样品中铜的测定，相对标准偏差在3.5%以内，回收率在96.7%~ 104.1%之间。 关键词:共振散射光谱法:铜:罗丹明6G; 面粉:茶叶 Determination of Copper in Flour and Tea by Resonance Light-Scattering Technique wi由 2 Cu + - Tungstate-Rhod缸nine 6G System SHAO Yating , MAO Zhicheng , WANG Peilin, CHEN Jin , CAO Qiu e * (Key Laboratory of Medicina1 Chemis町for Nature Resource, Ministry of Education, School of Chemica1 Science and Technology , Yunnan University, Kunming 65∞91， China) Abstract: 0均ective: To develop a method for the determination of copper in food samples. Methods: Resonance light- scattering technique was used. Results: The resonance light咽attering signa1 at 589 nm was observed when a ion-associated complex was formed among Cu2+, tungstate and rhodamine 6G in the presence of polyvinyl alcohol (pV A). The light- 2 scattering intensity increased linearly with increasing concentration of Cu + in the range of 0.05- 1.0 ng/mL. The linear regression equation was fj. 1 =4.38 + 77.12c (r =0.997 1), and the detection limit was 0.026 nglmL. The relative standard deviations and recovery rates o