ICP-OES法测定饮用天然矿泉水中总硬度.pdfVIP

食晶研究与持Jt 2016 年 10 月 检测分析 Food Research And Development 第 37 卷第 20 期 167. - DOI :10.3969/j.总so.I005-6521.2016.20.039 ICP-OES法测定饮用天然矿泉水中总硬度 马兴， 张静， 于尧， 郑文杰 (天津出入境检验检疫局，天津3∞461 ) 摘 要:开展ICP OES 法间接测定饮用天然矿泉水中总硬度的方法研究。 利用 ICP OES 法直接测定饮用天然矿泉水 中钙和佼离子的含量，然后通过相关计算得出待测样品的总硬度值。结采表明， ICP OES 测定钙的检测依为 7..8μf!/L， 线性系数为 0.9997 ，加标回收率在 98.1 %- 102.5 %之间;现~定绞离子的检现~f且为 3.9μ.g/L，线性系数为 0.9998 ，加标回收 率在 98 5 %-103.2 %之间。结论ICP OES 法与国标方法相比差异无统计学意义，并且ICP OES 法具有快速简便、准确 高效、抗千扰能力强等优点。 关键词:饮用天然矿泉水;也感祸合等离子体发射光译;总硬度;钙;绞 Determination of Total Har dness in Drinking Natural Minera l Water b y IC P - Q ES MA Xi吨， ZHANGJi吨， YUYao , ZHENG Wen-jie ( Tianjin Entrγ-Exit Inspection and Qua1antine Bureau , Tianjin 3∞461 ， China ) Abstract: To develop a method fo 1 dete1mination of total ha1dness in wate 1 by ICP -QES . Methods The total ha1dness in wate 1 was dete1mined indirecÙy. Fi1sÙY we deteITnined the total content of Ca and Mg with ICP- QES , then changing the 1esults to total ha1dness. Results The detect limit of Ca was 7.2μ包IL ， the linea1 C01re- lation was 0.999 7 , and the 1ecoverγrates was 98 .1 %- 102.5 % . The detect limit of Mg was 3.9μglL， the linea1 cOl1elation was 0.999 8 , and the 1ecove1y rates was 98.5 %- 103.2 % . Conclusion The1es no significant diffe 1- ence between the result s of ICP-QES and national standa1d method. Also the ICP-QES method has the advan- tages of rapid , accurate , simple and litÙe disturbance. Key wor ds : d1inking natural mine1al wate 1; ICP-QES;