ICP-MS法测定地表水中7种重金属元素含量.pdfVIP

安徽农业科学，Joumal of Anhui Agri. Sci.2016 ,44(6) :122 , 126 责任编辑陈红红责任校对况玲玲 ICP-MS 法测定地表水中 7 种重金属元素含量 刘卫面，刘欢欢，胡慧洁，赵昌平，赵杰 (江苏省苏州国环环境检测有限公司，江苏苏州 215删) 摘要 [目的]建立电感搞合等离子体质谱(ICP-MS) 同时测定地表水中 7 种重金属元素含量的方法。[方法]采用 ICP-MS 法，用 2% 74 HN0 Cd、 Cr、 Cu、民、Pb、Zn、Hg 浓度为 0，5.0、 10.0，20.0、40.0、50.0μ名IL 的标准系列，以Sc， Ge、In ， .Re 作在线内标，调节仪 配制 3 器测定参数，测定地表水环境质量标准基本项目中的重金属元素含量。[结果] ICP-MS 法测定的7 种重金属含量元素的线性相关系数 均 0.9990 ，标准样品的测定值均在保证值范围内，加标回收率为 95.5% -102.0%0 [结论]ICP-MS 法具有操作简便、干扰少、分析速 度快、灵敏度高、结采准确可靠等优点，是测定地表水中重金属元素含量的理想方法。 关键词 金属元素含量;电感丰离合等离子体质谱法;地表水 中图分类号 S181 文献标识码 A 交章编号 0517 -6611 (2016)06 -122 -01 SimuItan四郎Detem血ation or 7 Heavy MetaI Elements in Surface Water by ICP-MS LIU Wei-li , LIU Huan-huan , HU Hui才ie et al (Suzhou Guohuan Environment Detection Co. Ltd , Suzhou , Jiangsu 215酬) Abstract [0均ective] To establish an ICP-MS method for the 7 elements determinalion in su由ce water. [Method] Serial mixed standard so- lutions were prepared by 2% HN03 wi由 concentrations of Cd , Cr , Cu ，缸， Pb ， Zn , HgbeingO.O , 5.0 ， 10.0 ， 20.0 ， 40.0 ， 50.0μg1L .,Sc, 74 Ge, In , 85 Re was used as on-line inlemal stand缸ds and the instrument s parameters were adjusled to good state , Ihe metal ele- ments in the su由ce water environment quality standard basic project were determined. [Result] The linear correlative coefficients for 7 ele- ments were higher than O. 999 0 , testing values of standard reference materials were within guaranteed scope , spiked recoveries were between 95.5% and 102.0%. [Conclusion] 四e ICP-MS method is simple , quick , less interference , sensilive and accurate , it can be used as perfect method to determine metal elements content in surface water. Key words Metal elem