生物基锦纶环保加工技术及其应用.pdfVIP

第 36 卷第4 期 纺织学报 Vo 1. 36 , No.4 2015 年 4 月 Journal of Textile Research Ap r. , 2015 DOI:IO.13475/j.fzxb.20140405806 生物基锦纶环保加工技术及其应用 郝新敏，郭亚飞 (总后勤部军需装备研究所，北京 100082) 摘 要 生物基锦纶是指相对于传统石化法聚眈胶纤维，使用草麻油裂解法或葡萄糖发酵法等生物法合成加工得 到的绿色、环保型聚酌胶纤维。生物基锦纶具有传统锦纶的高强、耐磨、吸湿等优良性能，并在原料来源可持续、功 能性等方面存在很大优势，但多数由于成本过高或提取工艺不过关而未能实现产业化。近年来，蔑麻油裂解工艺 和葡萄糖生物发酵工艺取得了飞速的发展，尤其是我国大大提高了微生物发酵中关键酶的效率，使生物基锦纶单 体的成本和质量都得到控制，有助于打破长期以来国际公司对聚眈胶原料单体二元肢的市场垄断，具有现实的产 业化前景，在化纤工业、汽车行业和军事装备领域都有广阔的应用前景。 关键词 生物质;生物基锦纶;加工技术;产业化 中图分类号:TS 15;Q 185 文献标志码:A Environment-friendly processing technology and application of bio-based polyamide fiber HAO Xinmin , GUO Yafei (Th. e Quarterm. aster Research Jnst山te 0/ the Geneml Logistics Depαrlm.ent of th.e PLA , Beijing 100082 , Ch. inα) Abstract Relative to conventional petrochemical polyamide fiber , bio-based polyamide fiber is processed and obtained by a biological method such as castor oil cracking or glucose fermentation , and is green and environmental friendly. Bio-based polyamide fiber has excellent properties such as high strength , wear resistance and moisture absorption equivalent to conventional nylon fiber , and has big advantages in aspects of sustainable sources of raw materials , function , etc. But most of them is failed to industrialize due to overhigh cost and poor extraction process. In recent years , the castor oil cracking process and the glucose fermentation process have been developed rapidly. Especially the efficiency of key enzymes in the microbiological fermentation has been greatly improved domestica l1 y , so that