生物硫铁复合材料处理含铬废水及铬资源化研究.pdfVIP

中国环填科学 2009.29(12): 1260-1265 China Environmental Science 生物硫铁复合材料处理含铭废水及铭资源化研究 谢翼飞，卒旭东\亭描德(中闺科学院成都生物研究所，四川成都 610041) 摘要:研究了自毓酸就还J~~自(SRB)与其原位促成的纳米硫铁化合物组成的生物硫铁复合材料{生物硫铁}的耐铭性能和再坐性能，并利用 其再生特性，设计了处理而浓度含铭废水及锵资源化的还原市再生循环处E理工艺.结果表明，生物硫铁处理含格废水后，污泥中的 SRB 仍具有 3 很役，能以反!岐产物Fe 和$舶原为电子受休，官在新做成t物硫铁;而且SRB夜Cr(Vl)浓度6ωmgIL的废水中仍能得很并波斯将Cr(Vl)去除. 还原-~呼吁循环处磁工艺处现禽锵废*给果表明，出水 Cr(Vl)低于0.0l 9mgIL，总 Cr 低于0.929mgIL，能达标排放.经 10 个循环处坷，后f亏泥中 Cr 格( 20))含1世达到IJ40.47%，锡铁比达到 6.98，污犯达到j冶金级(湿$.冶炼储)络矿标准和化工级络矿你准，可资源化利用. 关键诩2 生物硫铁复合材料:硫自费盐还原吕西:锵(Vl); 1守锵废水s 资源化 中图分曾在哥哥I XS92 文献标识码:A 文章编号I 1000叮6923(2ω9)12ω12ω。6 Applica筒。，n of biological iron sulfide composites 汹 chromium-cont辑ining wastewater treatment and chromium reclamation. XIE Yi嗣fei， LI Xu-dong , LI Fu-de (Chengdu Institute ofBiolo即 Chinese Academy of Sciences, Chengdu 610041 , China). China Environmental Scie阳风2009，29(12): 1260-1265 Abstract: The resistanceωCr(VI) and regeneration character of biological iron sulfide composites were studied. The composítes consisted of sulfate reducíng bacteria(SRB) and nanosized iron sulfide produced by SRB, A new reduction-regeneration recirculation process for treating chromium-contain讪g wastewater and reclaiming chromium was developed with the regeneration character of the composites. The SRB still survived after tr四ting wastewater containing Cr(VI) , which could regenerate biological iron sulfide composi比s by using Fe3飞 sulphur as electron acceptor. Furthermore, the SRB could also resist 600mgIL Cr(VI) and remove 忧 gradually. The results of reduction-regeneration recirculation process for 衍eating wastewater indicated that the contaminants in the eftluent could meet the discharge standard, i.e. the concentration of total chromium le部 than 0.92如币gIL， Cr(VI) less than 0.019 mg!L. After 10 cycles,the Cr203 con阳1t in sludge reached 40 .47%, and the ratio of Cr203IFeO w