亚甲基蓝-Fenton体系光度法测定食品中没食子酸丙酯的含量.pdfVIP

中国食品添加剂 方析坝。试f 一 亚甲基蓝 -Fenton 体系光度法测定食品中 没食子酸丙醋的含量 谢宇奇，凌绍明\农丽梅 (百色学院化学与环境工程学院，百色 5330(0) 摘 要:在酸性溶液中，没食子酸丙醋对Fenton 试剂氧化亚甲基蓝褪色反应有明显的抑制作用，据此建 4 立了一种用分光光度法测定痕量没食子酸丙醋的新方法。在选定的实验条件下，方法的线性范围为 8.3 X 10- mg/mL - 1.3 x 1Q-2mg/mL，线性回归方程为ð.A665nm=42.666 p +0.0239 ，相关系数 (R2) = 0.9961 ，检出限 为1.5 x 1Q-4mg/mL。方法用于巧克力糖中 PG 的测定，测定结果的 RSD 为 4.29毛，回收率为 97.12% - 104.5%0 关键词.没食子酸丙醋g 亚甲基蓝g 光度法 I Fenton 试剂 中图分类号: TS202.3厅S207.3 文献标识码:B 文章编号: 1006-2513 (2016) 02-0141-05 Methylene Blue-Fenton spectrophotometry system of propyl 9创late detecting in food XIE Yu-qi , LING Shao-ming. , Nong Li-mei (College of chemical and environmental engineering , Baise University , Baise 533(0) Abstract: In acidic solution , propyl gallatec has obvious inhibitory effect on blue color fading in Fenton oxidation methylene reaction. Therefore , a spectrophotometry method of detecting propyl gallatec is established. Under the selected conditions , the method of the linear range was 8.3 x 10 气ng/mL - 1.3 x lQ-2mg/mL , linear regression equation was ð. A665nm= 42.666 + 42.666 , the correlation coefficient was (R2) = 0.9961 , detection lirnit was 1.5 4 x 1O- mg/mL. Method was used in the deterrnination of PG in chocolate candy , the deterrnination results of RSD was 4.2% , therecovery was 97.12% - 97.12% Key words: propyl gallate; methylene blue I spectrophotometry; Fenton reagent. 没食子酸丙醋(Propy 1 galla饨，简称PG) 致肾脏受损或引起接触性皮炎、唇和口周皮炎