凯里地区天胡荽中微量元素含量的测定.pdfVIP

安徽农业科学，Journal of Anhui Agri. Sci.2012 ,40(2) :712-7日，722 责任编辑夏静责任校对况玲玲 凯里地区天胡要中微量元素含量的测定 杨晓艳，王翔* (凯里学院应用化学研究所，贵州凯里 556011 ) 摘要 [目的]测定凯里地区天胡妾(Hydrocotyle sibtlwrpioides Larn. )样品中微量元素的含量。[方法]采用微波消解 火焰原子吸收光 谱法(FAAS) 、氢化物原子发生荧光光谱法 (HG-AFS) 测定夭胡英中Zn、 Cu 、 Fe、 Mn、 Se 5 种微量元素的含量。[结果]凯里下司地区的不 同颜色的天胡芸含有丰富的人体必需微量元素 Zn 、 Cu、 Fe、 Mn ， S吧，且含量依次是 Fe Mn Zn Cu Se; 其中绿色天胡芸中 Zn、 Cu 、 Fe 、 Mn 的含量几乎是红色天胡~含量的 2 倍，而 Se 含量差异不大，所测 Se 含量均大于0.110μglg ，属于高硝植物。所坝J 元素回收率在 98. 1 % - 104.2% 之间 ， RSD 在0.01% -2.22% 之间。[结论]该研究为当地夭胡芸药用价值的科学评价提供了依据。 关键词 天胡芸;微量元素;测定 中图分类号 R284.1 文献标识码 A 文章编号 0517 -6611(2012)但∞712 -02 Determination of Trace Elements in Hydroco砂le sibthorpioides Lam. of Kaili YANG Xiao-yan et aJ (Institute of Applied Chemist巧， Kaili University ,Kaili ,Guizhou 55ωll) Abstract [ Objective J To detennine the trace elements in Hydrocotyle sibtlwrpioides Larn. of Kaili. [Method J The contents of five trace elements including Zn ,Fe ,Cu ,Mn and Se in Hydrocotyle sibthorpioides Lam. were detennined by flame atomic abso叩tion spectromet町 (FAAS) and hy- dride generation atomic fluorescence spectrome盯(HG - AFS). [Result J Different colors of Hydrocotyle sibtlwrpioid臼Lam. from Xiasi of Kaili was rich in Zn ,Fe ,Cu ,Mn and Se which were essential to human body ,the contents of 5 trace elements decreased according to the following order Fe Mn Zn Cu Se; and the contents of Zn ,Cu ,Fe and Mn in green Hydrocotyle sibtlwrpio昨s Lam. were almost twice of that in red Hydro- cotyle si面tlwrpioides Lam. ,Se content changed insignificantly and the measured Se contents were all above .0. 口1 10 μg扩/g ， 巾ther，陀-ef岛or肥e Hy州drocot句刑y升le sibth凹P凶d命es Lam. was high seler山m plants. The recoveries and relative standard deviation (RSD) of these trace elements were among 98.1 % - 104. 2 % and 0.01 % - 2.22%