分光光度法测定地质样品中Mo的不确定度评定.pdfVIP

Vo l. 34 ，陆 2 第34卷第2期 学 计 量 报 2013 年 3 月 ACTA METROLOGICA SINICA March , 2013 doi: 10. 3969/j. issn.1000-1158.2013.02.20 分光光度法测定地质样品中 Mo 的不确定度评定 张激光 (国土资源部沈阳矿产资源监督检测中心，辽宁沈阳 11∞32) 摘要:通过对分光光度法测定地质样品中锢元素质量比全过程分析，确定了测定结果不确定度的来源并加以 评定。采用最小二乘法对标准曲线进行线性回归，通过对2 个不同质量分数样品的不确定度评定，证明样品的重 复性测定和标准曲线拟合引人的不确定度为总不确定度的主要贡献者，且样品 Mo 质量分数越低，其相对不确定度 越大，这与实验室中的实际测定情况一致。 关键词:计量学;地质样品;锢;分光光度法;不确定度评定;线性回归 中图分类号: TB99 文献标识码:A 文章编号: 1αlO-1158(2013 )02 -0 196-05 Unce时ainty Evaluation for the Determination of Mo in Geological Samples by Spectrophotometry ZHANG Ji-guang ( Shenyang Testing and Quality Supervision Center for Geological and Mineral Products , The Ministry of Land and Resources , Shenyang , Liaoning 11∞32 ， China) Abstract: The sources of measurement unce血inty for the anal严ical results of Mo content in geological samples by spectrophotometry is determined and sub-uncertainties of the analytical results a陀 evaluated through studying the whole process of the analytical results. With the least square method ,the calibration curve is fitted.ηlrough the evaluation of the anal严ical results of various contents of two samples , the sub-uncertainties from the sample repeated measures and the fitting of the calibration curve are the m句。r contributor to the expanded uncertainty. And it shows that the lower the concentrations of Mo , the greater the relative standard uncertainty of analyti