分散液液微萃取-分光光度法测定微量镍.pdfVIP

• 34 • D配.20口 Plating and Finìshing Vo l. 34 No. 12 Serial No.237 文章编号:1∞1-3849(2012)12-0034-04 分散液液微萃取·分光光度法测定微量镇 唐祝兴，薛君，陈寅，孙宇航 (沈阳理工大学环境与化学工程学院，辽宁沈阳 110159) 摘要:为快速、准确地，制定溶液中的微量蝶，以 2-(5-嗅-2- 吭吭偶氨)-5-( 二乙氨基)革酣为普合 剂，四氯化喋为革取剂，乙醇均分散剂，应用分散边液橄萃取分离富集槌量操，并对影响革取效果的 分散在旋微草取·分克尤皮法有效提高了 各因素进行分析，确定了最佳革取条件，富集倍数为 18 0 分析仪器的桂iJ11 能力，是瘟量元素的检测新方法，将其应用于革注中提量蝶的测定，结果令人满意。 关键匍:分散液坡橄革取;分尤尤皮法;操;现IJ 定 中固分类号: TG115. 335 立献标tR码:B Determination of Trace Nickel in Aqueous Solution by Dispersive Liquid- llquid Microextraction with Spectrophotometry TANG Zhu-xi吨， XUE Jun , CHEN Yín , SUN Yu-hang (Schω1 of Environmental and Chemical En回neeri吨， Shenyang Ligong University , Shenyang 110159 , China) Abstract: In this work , dispersive liquid-liquid microextraction 阻 a novel approach was developed for accurate and fast detemúnation of trace nickel in aqu回us solution by spectrophotometry. In the extraction method , 5 - Br- PADAP w回 used 臼 chelating agent , and CCl and C H圭 OH as extracting agent and dis- 4 2 persant , respectively. Some influencing factors on extraction efficiency were analyzed and the best extrac- tion and separation condition w国 detennined. The enrichment multiples was 18. 币lis method has heen successfully applied in the analysis of trace nickel in nickel plating w植te with satisfactory results. Keywords: DLLME; spectrophotometry; nickel; detennination 法之一，分析速度快、操作简单且戚本低廉，但是对 引言 于基体溶液复杂、目标分析物含量极低的样品，其 在电镀生产中，电镀液中杂质离子逐渐增多， 灵敏度往往达不到要