双误差回归在离子色谱法测定硫酸根不确定度评定中的应用.pdfVIP

.!. 4于 Vol. 34 , No 6 第34卷第6期 计 量 报 2013 年 11 月 ACTA METROLOGICA SINICA November , 2013 doi: 10. 3969/j. issn.1000-1158.2013.06.21 双误差回归在离子色谱法测定硫酸根 不确定度评定中的应用 俞建国， 周小红， 王华， 邓振平 (中国地质科学院岩溶地质研究所国土资源部岩溶动力学重点实验室，广西桂林 541∞4) 摘要:采用不确定度连续传递模式，建立了离子色谱法测定岩溶地下水中硫酸根分析结果不确定度的评定模 型。评定结果表明，测定结果的不确定度主要来源于标准溶液引人的不确定度、曲线拟合产生的不确定度和测定 过程引人的不确定度3 部分。采用x _y 的相对差，对校准曲线进行双误差回归，对评定过程中各个不确定度分量进 行量化，最后通过计算合成得到硫酸根测定结果的不确定度评定模型。 关键词:计量学;双误差回归;硫酸根;不确定度;离子色谱法 中图分类号: TB99 文献标识码:A 文章编号: 1 仪lO-1158 (2013 )06 .Q6 11 .Q6 The Application of Double - error Regression in Unce付ainty Evaluation Method for Sulfate Determination by lon Chromatography YU Jian-guo , ZHOU Xiao-hong , WANG Hua , DENG Zhen-ping (Institute of Karst Geology of CAGS , Karst Dynanics Laboratorγof MLR , Guilin , Guan伊i 541∞4 ， China) Abstract: An uncertainty evaluation method for sulfate determination in karst under伊)und water by ion chromatography detection technology is proposed. Using continuous propagation model of uncertainty , the sulfate measurement uncertainty is evaluated. The main sources of me咀surement uncertainty come from sub-uncertainties of calibration solutions ,calibration curve fitting and measureme盹 process. 四e double-error regression is used in the process of standard cu凹e fitting. Based on the quantitative analysis of each uncertainty component during experimental results ，也e standard uncertainty model for sulfate determination results is obtained.