添加氢气对LPG空气预混火焰结构的影响.pdfVIP

理化学学报(Wuli Huaxue Xuebao) July A cta Phys. Chim. Sin., 2008, 24(7) ：1137-1142 1137 [Article] 添加氢气对LPG/空气预混火焰结构的影响 彬彬 邱 榕 蒋 勇 (中国科学技术大学火灾科学国家重点实验室, 合肥 230026) 摘要： 针对氢气添加的LPG(液化石油气)+空气预混火焰结构进行了数值研究, 详细计算了在含氢比a 为0% 到45%、稀释引子D 为21%到16%条件下的自由蔓延火焰, 得到了不同燃烧条件( =0.7-1.4)下的绝热燃烧速率 变化规律. 由于LPG 中的主要成分为丙烷和丁烷, 作者针对C3 和C4 质提出了详细化学反应动力学系统, 并 针对氢气添加的丁烷燃烧过程进行了数值计算, 得到了与实验相一致的结果, 验证了改进的详细化学机理的有 效性. 此外, 进一步计算了对撞双火焰的加氢LPG 火焰, 更加深入地探讨了火焰拉伸对燃烧稳定性和温度的影 响, 重点研究了 在0.5 到0.7 的稀薄燃烧, 验证了氢气添加可以有效提高稀薄燃烧条件下熄火拉伸率, 扩大稀 薄燃烧的极限, 增加火焰的稳定性. 关键词： 液化石油气; 氢气添加; 绝热燃烧速度; 熄火拉伸率 中图分类号： O643 Effects of Hydrogen Enhancement in LPG/Air Premixed Flame WANG Bin Bin QIU Rong JIANG Yong (State Key Laboratory of Fire Science, University of Science and Technology of China, Hef ei 230026, P. R. China) Abstract ： A numerical study of hydrogen enhanced liquefied petroleum gas (LPG)+air flames was presented. The variations of the adiabatic burning velocity in different conditions of combustion ( =0.7-1.4) were studied extensively. The hydrogen content in the fuel was varied from 0% to 45% and the dilution factor was from 21% to 16%. Since the maj or components of LPG are butane and propane, an appropriate chemical kinetic model must be chosen to solve the chemical reaction of C3 and C4 species. Validation of the chemical kinetic model against the fundamental combustion data was performed